29304-86-7

Basic information

• Product Name: 1,3,5-Cycloheptatriene, 7-(4-chlorophenyl)-
• CAS NO: 29304-86-7
• Molecular Formula: C13H11Cl
• Molecular Weight: 202.683
• Mol File: 29304-86-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1,3,5-Cycloheptatriene, 7-(4-chlorophenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3,5-Cycloheptatriene, 7-(4-chlorophenyl)-(29304-86-7)
• EPA Substance Registry System: 1,3,5-Cycloheptatriene, 7-(4-chlorophenyl)-(29304-86-7)

Safety Data

• Hazardous Substances Data: 29304-86-7(Hazardous Substances Data)

Upstream product

• 106-39-8 bromochlorobenzene 
• 1714-39-2 7-ethoxy-1,3,5-cycloheptatriene 
• 1714-38-1 7-methoxy-1,3,5-cycloheptatriene 
• 27081-10-3 tropylium tetrafluoroborate 
• 25230-72-2 tropylium perchlorate 

Downstream Products

• 59183-25-4 1-(4-Chlorphenyl)-1,3,5-cycloheptatrien 
• 29304-91-4 2-(4-Chlorphenyl)-1,3,5-cycloheptatrien 
• 29304-92-5 3-(4-Chlorphenyl)-1,3,5-cycloheptatrien 
• 85773-78-0 (1S,5S)-4-(4-Chloro-phenyl)-6,7-dioxa-bicyclo[3.2.2]nona-2,8-diene 
• 85773-77-9 (1S,2S,3S,4R,5R)-3-(4-Chloro-phenyl)-6,7-dioxa-tricyclo[3.2.2.0^2,4]non-8-ene 
• 117954-07-1 1-chloro-4-((1R*,2R*)-2-(p-tolyl)cyclopropyl)benzene 
• 80565-30-6 4'-chlorobiphenyl-4-carbaldehyde 
• 153850-83-0 4'-chlorobiphenyl-2-carboxaldehyde 

Relevant articles and documents

Gold Catalysts Can Generate Nitrone Intermediates from a Nitrosoarene/Alkene Mixture, Enabling Two Distinct Catalytic Reactions: A Nitroso-Activated Cycloheptatriene/Benzylidene Rearrangement

Gold-catalyzed reactions of cycloheptatrienes with nitrosoarenes yield nitrone derivatives efficiently. This reaction sequence enables us to develop gold-catalyzed aerobic oxidations of cycloheptatrienes to afford benzaldehyde derivatives using CuCl and nitrosoarenes as co-catalysts (10-30 mol %). Our density functional theory calculations support a novel nitroso-activated rearrangement, tropylium → benzylidene. With the same nitrosoarenes, we developed their gold-catalyzed [2 + 2 + 1]-annulations between nitrosobenzene and two enol ethers to yield 5-alkoxyisoxazolidines using 1,4-cyclohexadienes as hydrogen donors.

Cyclopropanation with gold(I) carbenes by retro-Buchner reaction from cycloheptatrienes

Cationic gold(I) promotes the retro-Buchner reaction of 7-substituted 1,3,5-cycloheptatrienes, leading to gold(I) carbenes that cyclopropanate alkenes.