2936-70-1 Usage
Description
PHENYL-BETA-D-THIOGLUCOPYRANOSIDE is a chemical compound that serves as a reagent in the synthesis of oligosaccharides. It is particularly utilized in the preparation of lactosylation through cellulase-catalyzed reactions, which involve dialkoxytriazine-type glycosyl donors.
Uses
Used in Pharmaceutical Industry:
PHENYL-BETA-D-THIOGLUCOPYRANOSIDE is used as a reagent for the synthesis of oligosaccharides, specifically in the preparation of lactosylation. This application is crucial for the development of novel pharmaceutical compounds and therapeutic agents, as oligosaccharides play a significant role in various biological processes and can be used to target specific diseases.
Used in Biochemical Research:
In the field of biochemical research, PHENYL-BETA-D-THIOGLUCOPYRANOSIDE is employed as a reagent to study the mechanisms of enzymatic reactions, particularly those involving cellulase-catalyzed processes. This helps researchers gain insights into the structure, function, and regulation of enzymes, as well as the synthesis of complex carbohydrates.
Used in Food Industry:
PHENYL-BETA-D-THIOGLUCOPYRANOSIDE may also find applications in the food industry, where it can be used to develop new methods for the production of modified oligosaccharides. These modified oligosaccharides can have potential health benefits, such as prebiotic effects, and can be incorporated into various food products to enhance their nutritional value.
Overall, PHENYL-BETA-D-THIOGLUCOPYRANOSIDE is a versatile reagent with applications in various industries, including pharmaceuticals, biochemical research, and food production. Its role in the synthesis of oligosaccharides and the study of enzymatic reactions highlights its importance in the development of new therapeutic agents and the advancement of scientific knowledge.
Check Digit Verification of cas no
The CAS Registry Mumber 2936-70-1 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 2,9,3 and 6 respectively; the second part has 2 digits, 7 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 2936-70:
(6*2)+(5*9)+(4*3)+(3*6)+(2*7)+(1*0)=101
101 % 10 = 1
So 2936-70-1 is a valid CAS Registry Number.
InChI:InChI=1/C12H16O5S/c13-6-8-9(14)10(15)11(16)12(17-8)18-7-4-2-1-3-5-7/h1-5,8-16H,6H2
2936-70-1Relevant articles and documents
Synthesis of Glycosyl Fluorides by Photochemical Fluorination with Sulfur(VI) Hexafluoride
Bannykh, Anton,Khomutnyk, Yaroslav,Kim, Sungjin,Nagorny, Pavel
supporting information, p. 190 - 194 (2021/01/13)
This study describes a new convenient method for the photocatalytic generation of glycosyl fluorides using sulfur(VI) hexafluoride as an inexpensive and safe fluorinating agent and 4,4′-dimethoxybenzophenone as a readily available organic photocatalyst. This mild method was employed to generate 16 different glycosyl fluorides, including the substrates with acid and base labile functionalities, in yields of 43%-97%, and it was applied in continuous flow to accomplish fluorination on an 7.7 g scale and 93% yield.
Photooxidation of thiosaccharides mediated by sensitizers in aerobic and environmentally friendly conditions
Traverssi, Miqueas G.,Pe?é?ory, Alicia B.,Varela, Oscar,Colomer, Juan P.
, p. 9262 - 9273 (2021/03/16)
A series of β-d-glucopyranosyl derivates have been synthesized and evaluated in photooxidation reactions promoted by visible light and mediated by organic dyes under aerobic conditions. Among the different photocatalysts employed, tetra-O-acetyl riboflavin afforded chemoselectively the respective sulfoxides, without over-oxidation to sulfones, in good to excellent yields and short reaction times. This new methodology for the preparation of synthetically useful glycosyl sulfoxides constitutes a catalytic, efficient, economical, and environmentally friendly oxidation process not reported so far for carbohydrates.
Leveraging Trifluoromethylated Benzyl Groups toward the Highly 1,2- Cis-Selective Glucosylation of Reactive Alcohols
Njeri, Dancan K.,Ragains, Justin R.,Valenzuela, Erik Alvarez
supporting information, p. 8214 - 8218 (2021/11/13)
Here, we demonstrate that substitution of the benzyl groups of glucosyl imidate donors with trifluoromethyl results in a substantial increase in 1,2-cis-selectivity when activated with TMS-I in the presence of triphenylphosphine oxide. Stereoselectivity is dependent on the number of trifluoromethyl groups (4-trifluoromethylbenzyl vs 3,5-bis-trifluoromethylbenzyl). Particularly encouraging is that we observe high 1,2-cis-selectivity with reactive alcohol acceptors.
