29584-68-7

Basic information

• Product Name: 3'-phenyl-2'(E)-propenyl 2-propynoate
• Synonyms: 3'-phenyl-2'(E)-propenyl 2-propynoate
• CAS NO: 29584-68-7
• Molecular Weight: 186.21
• Mol File: 29584-68-7.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 3'-phenyl-2'(E)-propenyl 2-propynoate(CAS DataBase Reference)
• NIST Chemistry Reference: 3'-phenyl-2'(E)-propenyl 2-propynoate(29584-68-7)
• EPA Substance Registry System: 3'-phenyl-2'(E)-propenyl 2-propynoate(29584-68-7)

Safety Data

• Hazardous Substances Data: 29584-68-7(Hazardous Substances Data)

Upstream product

• 4407-36-7 (2E)-3-phenyl-2-propen-1-ol 
• 471-25-0 Propiolic acid 
• 104-54-1 3-Phenylpropenol 
• 920-38-7 sodium propargylate 
• 102-92-1 Cinnamoyl chloride 
• 4392-24-9 Cinnamyl bromide 

Downstream Products

• 40918-97-6 3-phenyl-2-propen-1-yl 3-phenylacrylate 
• 1379515-65-7 C₂₂H₁₇Cl₂NO₄ 
• 215119-35-0 C₂₂H₁₈ClNO₄ 
• 1379515-64-6 C₂₂H₁₈ClNO₄ 
• 1379515-66-8 C₂₃H₁₈F₃NO₄ 
• 1379515-85-1 C₂₅H₂₀Cl₂N₂O₄ 
• 215120-03-9 C₂₅H₂₁ClN₂O₄ 
• 1379515-84-0 C₂₅H₂₁ClN₂O₄ 
• 1379515-86-2 C₂₆H₂₁F₃N₂O₄ 
• 1379515-88-4 4-(3,5-dichloro-4-methoxyphenyl)-1,4-dihydropyridine-3,5-dicarboxylic acid 3-cinnamyl ester 5-(2-cyanoethyl) ester 
• 1379515-87-3 C₂₆H₂₃ClN₂O₅ 
• 1138619-11-0 (E,E)-3-phenylallyl 3-(2,4,6-trimethoxyphenyl)acrylate 
• 1138619-15-4 (E)-3-phenylallyl 3,3-bis-(2,4,6-trimethoxyphenyl)propanoate 
• 1138619-06-3 (E,E)-3-phenylallyl 3-(1H-indol-3-yl)acrylate 

Relevant articles and documents

INTRAMOLECULAR CYCLIZATION OF ALLYLIC PROPIOLATES MEDIATED BY THE ADDITION OF STANNYL RADICALS: A NEW SYNTHETIC ROUTE TO α-METHYLENE-γ-BUTYROLACTONES

Allylic propiolates react with tributyl- or triphenylstannane to yield α-(stannyl)methylene-γ-butyrolactones. α-Methylene-γ-butyrolactones are easily prepared by destannylation.

Stereoselective Synthesis of α-(Chloromethylene)-γ-butyrolactone Derivatives from Acyclic Allylic 2-Alkynoates

α-Methylene-γ-butyrolactones have been constructed by a bis(benzonitrile)palladium dichloride catalyzed cyclization reaction of the easily available acyclic 2'-alkenyl 2-alkynoates in the presence of CuCl2.A mechanism involving a stereoselective chloropalladation in the presence of CuCl2, followed by intramolecular insertion of a carbon-carbon double bond to the carbon-palladium bond, and subsequent CuCl2-mediated formation of a new carbon-chlorine bond is briefly discussed.