2973-30-0Relevant articles and documents
Copper-Containing Polyoxometalate-Based Metal-Organic Framework as a Catalyst for the Oxidation of Silanes: Effective Cooperative Catalysis by Metal Sites and POM Precursor
Ma, Xinyi,Jing, Zhen,Li, Kunhong,Chen, Yian,Li, Dandan,Ma, Pengtao,Wang, Jingping,Niu, Jingyang
supporting information, p. 4056 - 4061 (2022/03/03)
The oxidation of silanes into silanols is a very necessary transformation, and yet the rational fabrication of efficient catalysts for this reaction remains a challenging task. Here, a 3D polyoxometalate-based metal-organic framework (POMOF), [Cu3(pz)3{PMo12O40}]·H2O (HENU-8, HENU = Henan University; pz = pyrazine) was consciously prepared and first employed in the oxidation of dimethylphenylsilane with tert-butyl hydroperoxide (TBHP) as an oxidant, achieving 89% yield at a production rate of 132 mmol·g-1·h-1. Control experiments indicated that polyoxometalates and Cu atoms together affected the ultimate outcome in this catalytic system, and the designed catalyst followed a free radical mechanism.
New access to organoacyloxytrialkylsilanes
Mancardi, David,Sindt, Michele,Paul, Jean-Michel,Mieloszynski, Jean-Luc
, p. 3879 - 3884 (2008/02/10)
In this article, we present the synthesis of acetoxytributylsilane, obtained from methoxytributylsilane and acetic anhydride, under different conditions (catalyst, temperature, reaction time). Access to other acyloxytributylsilanes from different anhydrides is also presented. Copyright Taylor & Francis Group, LLC.