29910-09-6

Basic information

• Product Name: N-phenyltricyclo[2.2.1]heptane-2β,6β-dicarboximide
• Synonyms: N-phenyltricyclo[2.2.1]heptane-2β,6β-dicarboximide
• CAS NO: 29910-09-6
• Molecular Weight: 241.29
• Mol File: 29910-09-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-phenyltricyclo[2.2.1]heptane-2β,6β-dicarboximide(CAS DataBase Reference)
• NIST Chemistry Reference: N-phenyltricyclo[2.2.1]heptane-2β,6β-dicarboximide(29910-09-6)
• EPA Substance Registry System: N-phenyltricyclo[2.2.1]heptane-2β,6β-dicarboximide(29910-09-6)

Safety Data

• Hazardous Substances Data: 29910-09-6(Hazardous Substances Data)

Upstream product

• 129-64-6 3,6-endomethylene-1,2,3,6-tetrahydrophthalic anhydride 
• 62-53-3 aniline 
• 17812-27-0 cis-5-norbornene-endo-2,3-dicarboxylic anhydride 

Downstream Products

• 1175009-78-5 4-methylene-N-phenyltricyclo[5.2.1.02,6]decane-2β,6β-dicarboximide 
• 100937-47-1 (-)-(2R,3S)-3-endo-(hydroxymethyl)bicyclo<2.2.1>heptane-2-endo-carboxylic acid lactone 
• 95340-90-2 (+)-(2S,3R)-cis-endo-2,3-bis(hydroxymethyl)bicyclo<2.2.1>heptane-2-carboxylic acid lactone 

Relevant articles and documents

Desymmetrization of meso-cyclic imides via enantioselective monohydrogenation

meso-Cyclic imides are monohydrogenated to form the corresponding hydroxy lactams in 88-97% ee using trans-[Ru((R)-BINAP)(H)2((R,R)-dpen)] and related compounds as catalysts with base in THF. The hydrogenation proceeds with high enantiogroup-and chemoselectivity, and it is a desymmetrization reaction, forming up to five stereogenic centers in one reaction. Conversion of a hydroxy lactam into the corresponding iminium ion followed by addition of indene extended the number of stereogenic centers from 5 to 7.