311780-51-5

Basic information

• Product Name: [(C₅Me₅)Ir(PPh₂(C₆H₃-2-(MeO)-6-(OC(C₆H₄-4-COOMe)=CHCH=C(C₆H₄-4-COOMe))))](PF₆)
• CAS NO: 311780-51-5
• Molecular Weight: 1100.07
• Mol File: 311780-51-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(C₅Me₅)Ir(PPh₂(C₆H₃-2-(MeO)-6-(OC(C₆H₄-4-COOMe)=CHCH=C(C₆H₄-4-COOMe))))](PF₆)(CAS DataBase Reference)
• NIST Chemistry Reference: [(C₅Me₅)Ir(PPh₂(C₆H₃-2-(MeO)-6-(OC(C₆H₄-4-COOMe)=CHCH=C(C₆H₄-4-COOMe))))](PF₆)(311780-51-5)
• EPA Substance Registry System: [(C₅Me₅)Ir(PPh₂(C₆H₃-2-(MeO)-6-(OC(C₆H₄-4-COOMe)=CHCH=C(C₆H₄-4-COOMe))))](PF₆)(311780-51-5)

Safety Data

• Hazardous Substances Data: 311780-51-5(Hazardous Substances Data)

Upstream product

• 17084-13-8 potassium hexafluorophosphate 
• 75-09-2 dichloromethane 
• 228551-59-5 [(η(5)-pentamethylcyclopentadienyl)IrCl(Ph2PC6H3(O)OMe-2,6-κ(2)P,O)] 
• 3034-86-4 4-ethynylbenzoic acid methyl ester 

Relevant articles and documents

Novel single or double insertion of alkynes into rhodium- and iridium-oxygen or -phosphorus atom bonds and transannular addition of 1-alkynes between the rhodium atom and the ipso-carbon atom of the phosphorus ligand

Reactions of Cp*MCl(MDMPP-P,O) (1a: M = Rh; 1b: M = Ir; MDMPP-P,O = PPh2(C6H3-2-MeO-6-O)) or Cp*MCl(BDMPP-P,O) (2a: M = Rh; 2b: M = Ir; BDMPP-P,O = PPh(C6H3-2,6-(MeO)2)(C6H