313485-89-1

Basic information

• Product Name: 1H-Benzimidazol-1-amine, N-phenyl-
• CAS NO: 313485-89-1
• Molecular Formula: C13H11N3
• Molecular Weight: 209.25
• Mol File: 313485-89-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1H-Benzimidazol-1-amine, N-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1H-Benzimidazol-1-amine, N-phenyl-(313485-89-1)
• EPA Substance Registry System: 1H-Benzimidazol-1-amine, N-phenyl-(313485-89-1)

Safety Data

• Hazardous Substances Data: 313485-89-1(Hazardous Substances Data)

Upstream product

• 6299-92-9 1-aminobenzimidazole 
• 98-80-6 phenylboronic acid 
• 586-96-9 Nitrosobenzene 
• 62-53-3 aniline 
• 67-68-5 dimethyl sulfoxide 
• 2835-58-7 2-aminoazobenzene 
• 721-47-1 2'-Aminobenzanilid 
• 88-74-4 2-nitro-aniline 
• 728-90-5 N-(2-nitrophenyl)benzanilide 
• 7310-83-0 2- benzoylaminoazobenzene 
• 7647-01-0 hydrogenchloride 
• 50-00-0 formaldehyd 
• 64-19-7 acetic acid 
• 17082-12-1 trans-azobenzene 

Downstream Products

• 74936-84-8 2-Phenyl-azo-N-methylanilin 
• 313486-10-1 1-(N-acetyl-N-phenylamino)benzimidazole 

Relevant articles and documents

Method for arylation of the amino group in N-aminoazoles [3]

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Site-Selective C–H Amidation of Azobenzenes with Dioxazolones under Rhodium Catalysis

The rhodium(III)-catalyzed amidation reaction of azobenzenes with dioxazolones is described. This strategy allows the facile and efficient construction of highly substituted ortho-amidated azobenzenes by direct C–H cleavage approach. A wide range of substrates, excellent levels of chemoselectivity as well as high functional-group tolerance were observed. In addition, this protocol was used to generate an array of ortho-amidated ketazines. Further synthetic transformation of amidated azobenzenes furnished a facile construction of benzimidazole and benzotriazole derivatives.