31599-59-4

Basic information

• Product Name: 2-(diacetoxyiodo)toluene
• Synonyms: 2-(diacetoxyiodo)toluene
• CAS NO: 31599-59-4
• Molecular Weight: 336.126
• Mol File: 31599-59-4.mol
• Article Data: 21

Chemical Properties

• CAS DataBase Reference: 2-(diacetoxyiodo)toluene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(diacetoxyiodo)toluene(31599-59-4)
• EPA Substance Registry System: 2-(diacetoxyiodo)toluene(31599-59-4)

Safety Data

• Hazardous Substances Data: 31599-59-4(Hazardous Substances Data)

Upstream product

• 79-21-0 peracetic acid 
• 615-37-2 ortho-methylphenyl iodide 
• 64-19-7 acetic acid 
• 108-24-7 acetic anhydride 
• 108-88-3 toluene 
• 127-09-3 sodium acetate 

Downstream Products

• 131251-51-9 1-(2-iodo-3-methylphenyl)-3-(trimethylsilyl)-2-propyne 
• 131251-52-0 1-(3-iodo-2-methylphenyl)-3-(trimethylsilyl)-2-propyne 
• 73177-97-6 -o-toluene 
• 87167-83-7 2-methylphenyliodine bis(trifluoroacetate) 
• 85925-37-7 (5-methyl-2-furyl)(o-tolyl)iodonium tosylate 
• 85925-51-5 (2-Furyl)(2-methylphenyl)iodonium Tosylate 
• 1039396-18-3 (E)-1-methyl-3-(phenyl(o-tolyl)methylene)indolin-2-one 
• 1222532-05-9 (2,4,6-trimethylphenyl)(2'-methylphenyl)iodonium tosylate 
• 615-37-2 ortho-methylphenyl iodide 
• 1428540-97-9 (Z)-2-((E)-styryl)hex-1-en-1-yl trifluoromethanesulfonate 
• 1428541-01-8 (1Z,3E)-1-cyclopentyl-4-phenylbuta-1,3-dien-1-yl trifluoromethanesulfonate 
• 1428541-02-9 (1Z,3E)-2-cyclopentyl-4-phenylbuta-1,3-dien-1-yl trifluoromethanesulfonate 
• 1428541-15-4 (E)-styryl(o-tolyl)-λ³-iodanyl trifluoromethanesulfonate 

Relevant articles and documents

Conformational structure and energetics of 2- methylphenyl(2′methoxyphenyl)iodonium chloride: Evidence for solution clusters

Diaryliodonium salts allow the efficient incorporation of cyclotronproduced [18F]fluoride ions into electron-rich and electron-deficient arenes to provide potential radiotracers for molecular imaging in vivo with positron emission tomography (P

Applications of hypervalent iodine(III) reagents in constructing ortho-iodo aromatic ethers

A one-pot method for the synthesis of aromatic ethers using hypervalent iodine(III) reagents obtained from the corresponding iodoaryl compounds is developed. In this concise method, six diaryl ethers and three heterocyclic aromatic ethers are synthesized in good yields. Furthermore, possible mechanisms for the syntheses of the hypervalent iodine reagents and construction of the aromatic ethers are proposed.

N -Heterocyclic Carbene-Catalyzed Olefination of Aldehydes with Vinyliodonium Salts to Generate α,β-Unsaturated Ketones

An organocatalyzed metal-free, direct olefination of aldehydes with vinyliodonium salts has been achieved by an N-heterocyclic carbene-promoted C-H bond activation. The reaction proceeds under very mild conditions, delivering a range of (hetero)aryl-vinyl ketones in good yields. The retention of the double bond configuration is uniformly observed, and the application of 2-methoxyphenyl auxiliary group in iodonium salts secures a complete selectivity of the vinyl transfer.