32276-00-9 Usage
Description
S,S-bis(1-phenyl-1H-tetrazol-5-yl) dithiocarbonate is a chemical compound characterized by the molecular formula C14H10N8S2. It features two tetrazole groups, which are five-membered aromatic rings with four nitrogen atoms and one carbon atom, attached to a dithiocarbonate group that consists of two carbonyl groups bonded to a central sulfur atom. This versatile reagent is known for its potential applications across various scientific fields, including coordination chemistry, medicinal chemistry, and materials science.
Uses
Used in Organic Synthesis:
S,S-bis(1-phenyl-1H-tetrazol-5-yl) dithiocarbonate serves as a reagent in organic synthesis, facilitating the formation of complex organic molecules and contributing to the advancement of chemical research and development.
Used as a Source of Tetrazolylthiolate Ligands:
In coordination chemistry, S,S-bis(1-phenyl-1H-tetrazol-5-yl) dithiocarbonate is utilized as a source of tetrazolylthiolate ligands. These ligands are valuable for the formation of metal complexes, which have applications in catalysis, sensing, and other areas of chemistry.
Used in Medicinal Chemistry:
S,S-bis(1-phenyl-1H-tetrazol-5-yl) dithiocarbonate's unique structure and properties make it a promising candidate for medicinal chemistry, where it can be used in the development of new pharmaceuticals and therapeutic agents.
Used in Materials Science:
S,S-bis(1-phenyl-1H-tetrazol-5-yl) dithiocarbonate also finds applications in materials science, where it can be employed in the design and synthesis of novel materials with specific properties for various technological applications.
Check Digit Verification of cas no
The CAS Registry Mumber 32276-00-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,2,2,7 and 6 respectively; the second part has 2 digits, 0 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 32276-00:
(7*3)+(6*2)+(5*2)+(4*7)+(3*6)+(2*0)+(1*0)=89
89 % 10 = 9
So 32276-00-9 is a valid CAS Registry Number.
InChI:InChI=1/C15H10N8OS2/c24-15(25-13-16-18-20-22(13)11-7-3-1-4-8-11)26-14-17-19-21-23(14)12-9-5-2-6-10-12/h1-10H
32276-00-9Relevant articles and documents
A mild method for the protection of alcohols using a para-methoxybenzylthio tetrazole (PMB-ST) under dual acid-base activation
Kotturi, Santosh R.,Tan, Jason S.,Lear, Martin J.
supporting information; experimental part, p. 5267 - 5269 (2009/12/24)
With a view to expand the repertoire of chemoselective methods applicable to sensitive and multifunctional substrates, the p-methoxybenzylation of alcohols under essentially neutral conditions is reported. This was achieved by the silver triflate (AgOTf) activation of 5-(p-methoxybenzylthio)-1-phenyl-1H-tetrazole (PMB-ST) in the presence of 2,6-di-tert-butyl-4-methylpyridine (DTBMP).
S,S'-Bis(1-phenyl-1H-tetrazol-5-yl) Dithiocarbonate: A New Esterification Reagent
Takeda, Kazuyoshi,Tsuboyama, Kanoko,Takayanagi, Hiroaki,Ogura, Haruo
, p. 560 - 562 (2007/10/02)
S,S'-Bis(1-phenyl-1H-tetrazol-5-yl) dithiocarbonate is a useful reagent for the esterification of carboxylic acids with alcohols, including lactonization.The reagent is conveniently prepared in good yield from 1-phenyl-5-thioxo-4,5-dihydro-1H-tetrazole and trichloromethyl chloroformate (trichloromethyl carbonochloridate) in ethyl acetate in the presence of triethylamine.Its structure was confirmed by (13)C-NMR spectrometry and single-crystal X-ray analysis.
