32498-74-1

Basic information

• Product Name: 2-(benzyloxy)-5-methyl-1,3-dinitrobenzene
• Synonyms: 2-(benzyloxy)-5-methyl-1,3-dinitrobenzene
• CAS NO: 32498-74-1
• Molecular Weight: 288.26
• Mol File: 32498-74-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-(benzyloxy)-5-methyl-1,3-dinitrobenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(benzyloxy)-5-methyl-1,3-dinitrobenzene(32498-74-1)
• EPA Substance Registry System: 2-(benzyloxy)-5-methyl-1,3-dinitrobenzene(32498-74-1)

Safety Data

• Hazardous Substances Data: 32498-74-1(Hazardous Substances Data)

Upstream product

• 609-93-8 2,6-dinitro-p-cresol 
• 100-39-0 benzyl bromide 
• 620-05-3 iodomethylbenzene 

Downstream Products

• 6393-42-6 4-methyl-2,6-dinitroaniline 
• 100-51-6 benzyl alcohol 

Relevant articles and documents

Catalytic Enantioselective Synthesis and Switchable Chiroptical Property of Inherently Chiral Macrocycles

We report herein a strategy to construct enantiopure inherently chiral macrocycles, ABCD-type heteracalix[4]aromatics, through a catalytic enantioselective intramolecular C-N bond forming reaction. A chiral ligand-palladium complex was found to efficiently induce the inherent chirality of molecules during the macrocyclization process with ee values up to >99%. The resulting ABCD-type heteracalix[4]aromatics displayed excellent and pH-triggered switchable electronic circular dichroism and circularly polarized luminescence properties.