33284-52-5Relevant articles and documents
Sustainable Synthesis of Biaryls Using Silica Supported Ferrocene Appended N-Heterocyclic Carbene-Palladium Complex
Khanapure, Sharanabasappa,Pore, Dattaprasad,Jagadale, Megha,Patil, Vaishali,Rashinkar, Gajanan
, p. 2237 - 2249 (2021/01/11)
Abstract: A novel silica supported ferrocene appended N-heterocyclic carbene-palladium complex (SilFemBenzNHC@Pd) has been prepared and characterized by using fourier transform infrared (FT-IR), fourier transform Raman (FT-Raman), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), thermogravimetric analysis (TGA) and energy dispersive X-ray analysis (EDX). This novel complex served as a robust heterogeneous catalyst for the synthesis of biaryls via homocoupling of aryl boronic acids under base-free conditions in water. Recyclability experiments were executed successfully for six successive runs. Graphic Abstract: [Figure not available: see fulltext.]
Homocoupling reactions of terminal alkynes and arylboronic compounds catalyzed by in situ formed Al(OH)3-supported palladium nanoparticles
Li, Xing,Li, Dongjun,Bai, Yana,Zhang, Congxia,Chang, Honghong,Gao, Wenchao,Wei, Wenlong
supporting information, p. 6996 - 7002 (2016/10/14)
Palladium nanoparticles supported on newly generated Al(OH)3was found to be a highly efficient catalyst in oxidative homo-couplings of (Het)aryl alkynes, (Het)arylboronic acids and potassium (Het)aryltrifluoroborates, respectively. Moderate to excellent yields of symmetrical 1,3-diynes and biaryls were obtained under mild conditions.
Homocoupling of arylboronic acids with a catalyst system consisting of a palladium(II) N-heterocyclic carbene complex and p-benzoquinone
Yamamoto, Yoshihiko
, p. 1913 - 1916 (2008/03/13)
In the presence of 1-3 mol% SIPr-ligated Pd(OAc)2 and 0.6 equivalent of p-benzoquinone, various arylboronic acids underwent homocoupling in MeOH at ambient temperature to produce symmetrical biaryls in 38-96% yields. Georg Thieme Verlag Stuttgart.