34009-05-7

Basic information

• Product Name: Benzene, (octylsulfonyl)-
• CAS NO: 34009-05-7
• Molecular Formula: C14H22O2S
• Molecular Weight: 254.393
• Mol File: 34009-05-7.mol
• Article Data: 15

Chemical Properties

• CAS DataBase Reference: Benzene, (octylsulfonyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (octylsulfonyl)-(34009-05-7)
• EPA Substance Registry System: Benzene, (octylsulfonyl)-(34009-05-7)

Safety Data

• Hazardous Substances Data: 34009-05-7(Hazardous Substances Data)

Upstream product

• 111-85-3 n-chlorooctane 
• 873-55-2 sodium benzenesulfonate 
• 111-87-5 octanol 
• 111-27-3 hexan-1-ol 
• 5535-48-8 PVS 
• 3839-35-8 4-methylbenzenesulfonic acid n-hexylester 
• 1212-08-4 S-Phenyl benzenethiosulfonate 
• 111-83-1 1-bromo-octane 
• 13910-16-2 n-octylsulfanylbenzene 
• 7795-95-1 octane-1-sulfonyl chloride 
• 108-98-5 thiophenol 
• 426-58-4 (trifluoromethylsulfonyl)benzene 
• 17049-49-9 octylmagnesium bromide 
• 135885-52-8 1,2-Bis-(octane-1-sulfonyl)-benzene 

Downstream Products

• 88703-51-9 4-(Phenylsulfonyl)-2-methyl-1-hydroxyundecan-3-one 
• 88703-56-4 7-(Phenylsulfonyl)-1-hydroxytetradecan-6-one 
• 24388-23-6 2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole 
• 135581-33-8 Selenobenzoic acid O-(2-benzenesulfonyl-1-phenethyl-nonyl) ester 
• 144432-94-0 (E)-undec-3-en-1-ylbenzene 
• 74692-95-8 7-benzoyloxy-8-phenylsulphonylpentadecane 
• 135581-32-7 Selenobenzoic acid O-(2-benzenesulfonyl-1-hexyl-nonyl) ester 
• 26902-68-1 1,1,1-trifluorodecan-2-one 
• 853569-39-8 3-benzenesulfonyl-1,1,1-trifluoro-decan-2-one 
• 135581-30-5 Dithiocarbonic acid O-(2-benzenesulfonyl-1-phenethyl-nonyl) ester S-methyl ester 

Relevant articles and documents

Alkylation of Nitropyridines via Vicarious Nucleophilic Substitution

Electrophilic nitropyridines react with sulfonyl-stabilized carbanions to give products of C-H alkylation via vicarious nucleophilic substitution. The process consists of formation of the Meisenheimer-type adduct followed by base-induced β-elimination of the sulfinic acid (e.g., PhSO2H). Mechanistic studies reveal that in the latter step alkyl substituent and adjacent nitro group tend to planarize for effective stabilization of benzyl anion, and thus, adduct of hindered isopropyl carbanion remains stable toward elimination for steric reasons.

Cu-mediated: vs. Cu-free selective borylation of aryl alkyl sulfones

A Cu-catalysed borylation of aryl alkyl sulfones was developed for the high yield synthesis of versatile arylboronic esters using a readily prepared NHC-Cu catalyst. In addition, the selective cleavage of either alkyl(C)-sulfonyl or aryl(C)-sulfonyl bonds

MANUFACTURING METHOD OF COMPOUND HAVING SULFONYL GROUP

The present invention relates to a method for manufacturing a compound having a sulfonyl group, which includes a step for reacting thiosulfonates in a solvent comprising nucleophilic bases with an electrophilic agent. Accordingly, the present invention can manufacture the compound having the sulfonyl group with a variety of structures with high efficiency and high yield through more simplified processes than conventional methods.COPYRIGHT KIPO 2018