3416-93-1

Basic information

• Product Name: Benzenamine, 2-(4,5-dihydro-2-oxazolyl)-
• Synonyms: BEN354
• CAS NO: 3416-93-1
• Molecular Formula: C9H10N2O
• Molecular Weight: 162.191
• Mol File: 3416-93-1.mol
• Article Data: 32

Chemical Properties

• Melting Point: 55-56 °C (decomp)
• Boiling Point: 324.8±25.0 °C(Predicted)
• Density: 1.26±0.1 g/cm3(Predicted)
• CAS DataBase Reference: Benzenamine, 2-(4,5-dihydro-2-oxazolyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, 2-(4,5-dihydro-2-oxazolyl)-(3416-93-1)
• EPA Substance Registry System: Benzenamine, 2-(4,5-dihydro-2-oxazolyl)-(3416-93-1)

Safety Data

• Hazardous Substances Data: 3416-93-1(Hazardous Substances Data)

Upstream product

• 88186-34-9 4,5-dihydro-2-(2-nitrophenyl)oxazole 
• 610-14-0 2-nitrobenzyl chloride 
• 1570134-65-4 N-(2-(4,5-dihydrooxazol-2-yl)phenyl)-3-methoxybenzamide 
• 98-10-2 benzenesulfonamide 
• 1570135-37-3 N-(2-(4,5-dihydrooxazol-2-yl)phenyl)-2-((4-nitrophenyl)amino)benzamide 
• 7127-19-7 2-phenyl-1,3-oxazoline 
• 189075-69-2 N-(2-(4,5-dihydrooxazol-2-yl)phenyl)-2-fluorobenzamide 
• 1570135-20-4 N-(2-(4,5-dihydrooxazol-2-yl)phenyl)-2-(4-methylphenylsulfonamido)-4-vinylbenzamide 
• 1570135-19-1 4-acetyl-N-(2-(4,5-dihydrooxazol-2-yl)phenyl)-2-(4-methylphenylsulfonamido)benzamide 
• 1570135-18-0 N-(2-(4,5-dihydrooxazol-2-yl)phenyl)-2-(4-methylphenylsulfonamido)-5-(trifluoromethyl)benzamide 
• 1570135-17-9 N-(2-(4,5-dihydrooxazol-2-yl)phenyl)-2-(4-methylphenylsulfonamido)-4-(trifluoromethyl)benzamide 
• 1570135-16-8 N-(2-(4,5-dihydrooxazol-2-yl)phenyl)-2-(4-methylphenylsulfonamido)-6-(trifluoromethyl)benzamide 
• 1570135-14-6 4-bromo-N-(2-(4,5-dihydrooxazol-2-yl)phenyl)-2-(4-methylphenylsulfonamido)benzamide 
• 1570135-13-5 4-chloro-N-(2-(4,5-dihydrooxazol-2-yl)phenyl)-2-(4-methylphenylsulfonamido)benzamide 

Downstream Products

• 100135-35-1 [2-(4,5-dihydro-oxazol-2-yl)-phenyl]-carbamic acid ethyl ester 
• 3770-67-0 N-[2-(4,5-dihydrooxazol-2-yl)phenyl]-4-methylbenzenesulfonamide 
• 21900-42-5 2,4-dimethylbenzoyl chloride 
• 1711-05-3 m-anisoyl chloride 
• 100-07-2 4-methoxy-benzoyl chloride 
• 14002-51-8 4-biphenyl-carboxylic acid chloride 
• 879-18-5 naphthalene-1-carbonic acid chloride 
• 393-52-2 2-Fluorobenzoyl chloride 
• 1711-07-5 3-fluorobenzoyl chloride 
• 403-43-0 4-fluorobenzoyl chloride 
• 618-46-2 m-Chlorobenzoyl chloride 
• 122-01-0 4-chloro-benzoyl chloride 
• 586-75-4 4-chlorobenzoyl chloride 
• 312-94-7 2-trifluoromethylbenzoyl chloride 

Relevant articles and documents

Rhodium(III)-catalyzed chemodivergent annulations between phenyloxazoles and diazos via C–H activation

Acid-controlled, chemodivergent and redox-neutral annulations for the synthesis of isocoumarins and isoquinolinones have been realized via Rh(III)-catalyzed C[sbnd]H activation. Diazo compounds act as a carbene precursor, and coupling occurs in one-pot process, where adipic acid and trimethylacetic acid promote chemodivergent cyclizations.

Copper mediated C(sp2)-H amination and hydroxylation of phosphinamides

Copper mediated C(sp2)-H amination and hydroxylation of arylphosphinic acid are accomplished by adopting phosphinamide as the directing group. This method is distinguished by its wide substrate scope and excellent functional group tolerance, th

Synthesis of quinazoin-4-ones through an acid ion exchange resin mediated cascade reaction

An interesting cascade reaction of N-(2-(4,5-dihydrooxazol-2-yl)phenyl)benzamide in the presence of an acid ion exchange resin is described. In this reaction, a range of substrates bearing various substituent groups are well compatible. This work provides a green and atom-economical alternative approach for the synthesis of quinazolin-4-ones in good yields.