34176-92-6

Basic information

• Product Name: 3-Chlorobibenzyl
• Synonyms: 3-Chlorobibenzyl
• CAS NO: 34176-92-6
• Molecular Formula: C₁₄H₁₃Cl
• Molecular Weight: 0
• Mol File: 34176-92-6.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 289.9°C at 760 mmHg
• Flash Point: 117.4°C
• Appearance: /
• Density: 1.111g/cm³
• Vapor Pressure: 0.00372mmHg at 25°C
• Refractive Index: 1.583
• CAS DataBase Reference: 3-Chlorobibenzyl(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Chlorobibenzyl(34176-92-6)
• EPA Substance Registry System: 3-Chlorobibenzyl(34176-92-6)

Safety Data

• Hazardous Substances Data: 34176-92-6(Hazardous Substances Data)

Usage

InChI:InChI=1/C14H13Cl/c15-14-8-4-7-13(11-14)10-9-12-5-2-1-3-6-12/h1-8,11H,9-10H2

Upstream product

• 5182-44-5 2-(3-chlorophenyl)ethanol 
• 84648-15-7 C₁₆H₁₃ClO₄ 
• 73178-50-4 1-(m-Chlorphenyl)-3-phenyl-propanon-⁽²⁾ 
• 14064-43-8 (E)-3-chlorostilbene 
• 108-42-9 3-chloro-aniline 
• 108-41-8 1-chloro-3-methylbenzene 
• 108-88-3 toluene 
• 927-83-3 di-t-butyldiazene 
• 5182-43-4 1-chloro-3-(2-chloroethyl)benzene 
• 71-43-2 benzene 

Relevant articles and documents

Structure of ω-Arylalkyl Radicals: A 13C CIDNP Investigation

Thermolysis of a series of ω-arylalkanoyl m-chlorobenzoyl (and acetyl) peroxides at ca. 100 deg C in cyclohexanone and in hexachloroacetone was studied by using 13C chemically induced dynamic nuclear polarization.Analysis of the observed 13C polarizations indicate that all the three radicals (β-arylethyl, γ-arylpropyl and δ-arylbutyl) have open-chain structures with no evidence for aryl participation resulting in spirocycloalkylcyclohexadienyl radicals.

Chemistry of the tert-Butyl Radical: Polar Character, ρ Value for Reaction with Toluenes, and the Effect of Radical Polarity on the Ration of Benzylic Hydrogen Abstraction to Addition to Aromatic Rings

We have reexamined the reactions of tert-butyl radicals with toluenes and have obtained a ρ value of 0.49 +/- 0.04 at 80 deg C.The new, independent system involves the quantification of all of the principal products from the reaction of tert-butyl radicals with mixtures of toluene and substituted toluene.Five major products contain benzyl fragments and are formed in significant yields: two symmetrical bibenzyls, the cross bibenzyl, and the two neopentylbenzenes that result from combination of tert-butyl and the two benzyl radicals.Attack on the side chain is a major reaction of free tert-butyl radicals and is the only significant reaction that they undergo other than cage and termination reactions. tert-Butyl radicals do not add to the ring of toluenes.Data on the relative rates of addition to benzenes and hydrogen abstraction from toluenes are collected for a series of radicals including hydrogen atoms; methyl, isopropyl, and tert-butyl radicals; and p-nitrophenyl, p-bromophenyl, and phenyl radicals.The data demonstrate that more electrophilic radicals have a larger tendency to add to rings whereas more nucleophilic radicals have a larger tendency to abstract benzylic hydrogens.