34645-31-3

Basic information

• Product Name: (3E,5E)-6-phenylhexa-3,5-dien-2-ol
• CAS NO: 34645-31-3
• Molecular Weight: 174.243
• Mol File: 34645-31-3.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: (3E,5E)-6-phenylhexa-3,5-dien-2-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (3E,5E)-6-phenylhexa-3,5-dien-2-ol(34645-31-3)
• EPA Substance Registry System: (3E,5E)-6-phenylhexa-3,5-dien-2-ol(34645-31-3)

Safety Data

• Hazardous Substances Data: 34645-31-3(Hazardous Substances Data)

Upstream product

• 4173-44-8 1-phenyl-1,3-hexadien-5-one 
• 555-31-7 aluminum isopropoxide 
• 4173-44-8 (E,E)-6-phenyl-3,5-hexadien-2-one 
• 58927-78-9 (2E,4E)-1-phenyl-2,4-hexadien-1-ol 
• 79299-29-9 (E)-1-phenyl-1,5-hexadien-3-ol 
• 598-32-3 2-hydroxy-3-butene 

Downstream Products

• 112087-67-9 1,3,3a,4,5,7a-hexahydro-1-methyl-3-oxo-5-phenylisobenzofuran-4-carboxylic acid methyl ester 
• 1071994-45-0 (S,3E,5E)-6-phenylhexa-3,5-dien-2-ol 
• 326804-29-9 (R,3E,5E)-6-phenyl-3,5-hexadien-2-yl acetate 
• 1009809-26-0 ethyl (3E,5E)-6-phenyl-hexadien-2-yl carbonate 
• 1354701-42-0 ((1E,3E)-5-azidohexa-1,3-dienyl)benzene 

Relevant articles and documents

Polymer-bound palladium-catalyzed coupling of allylic alcohols with hypervalent iodonium salts

The polymer-bound palladium catalyzed cross-coupling reaction of allylic alcohols with hypervalent iodonium sails to form carbon-carbon bonds was achieved at room temperature under extremely mild and aqueous conditions even in the absence of base with very high activity in the Stille coupling reaction. The polymeric catalyst can be easily separated from a reaction mixture and reused more than 10 times with no decrease in activity.

Palladium-catalyzed dienylations of chelated enolates

Isomerization-free reactions of dienyl carbonates with chelated amino acid ester enolates at -78 °C provide important information concerning the mechanism of these dienylations. The formation of regioisomeric products can be explained by competing SN2/SN2′ reactions, and the product distribution can be influenced by the proper choice of the reaction conditions. Chiral allylic substrates show a significant transfer of chirality. Wiley-VCH Verlag GmbH & Co. KGaA, 2008.

Reshuffling of functionalities catalyzed by a ruthenium complex in water

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