34904-92-2

Basic information

• Product Name: Ethanone, 2-(3,5-dimethoxyphenyl)-2-hydroxy-1-phenyl-
• CAS NO: 34904-92-2
• Molecular Formula: C16H16O4
• Molecular Weight: 272.301
• Mol File: 34904-92-2.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: Ethanone, 2-(3,5-dimethoxyphenyl)-2-hydroxy-1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 2-(3,5-dimethoxyphenyl)-2-hydroxy-1-phenyl-(34904-92-2)
• EPA Substance Registry System: Ethanone, 2-(3,5-dimethoxyphenyl)-2-hydroxy-1-phenyl-(34904-92-2)

Safety Data

• Hazardous Substances Data: 34904-92-2(Hazardous Substances Data)

Upstream product

• 108-86-1 bromobenzene 
• 144758-83-8 α-(3,5-dimethoxyphenyl)-α-(trimethylsilyloxy)acetonitrile 
• 7311-34-4 3,5-dimethoxybenzaldehdye 
• 151-50-8 potassium cyanide 
• 92989-59-8 (3,5-dimethoxyphenyl)(2-phenyl-[1,3]-dithian-2-yl)-methanol 
• 100-52-7 benzaldehyde 
• 198345-21-0 1-(3,5-dimethoxyphenyl)-2-oxo-2-phenylethyl benzoate 
• 5425-44-5 2-Phenyl-[1,3]dithiane 
• 100-58-3 phenylmagnesium bromide 

Downstream Products

• 144758-84-9 2-(α-Hydroxy-3,5-dimethoxybenzyl)-2-phenyl-1,3-dioxolane 
• 1054645-74-7 Phosphorous acid allyl ester (2R,3S,5R)-2-(tert-butyl-diphenyl-silanyloxymethyl)-5-(6-oxo-1,6-dihydro-purin-9-yl)-tetrahydro-furan-3-yl ester 1-(3,5-dimethoxy-phenyl)-2-oxo-2-phenyl-ethyl ester 
• 1054682-46-0 Phosphorous acid (2R,3S,5R)-2-(tert-butyl-diphenyl-silanyloxymethyl)-5-(6-oxo-1,6-dihydro-purin-9-yl)-tetrahydro-furan-3-yl ester 2-cyano-ethyl ester 1-(3,5-dimethoxy-phenyl)-2-oxo-2-phenyl-ethyl ester 
• 1053701-97-5 {1-[(2R,4S,5R)-4-{Allyloxy-[1-(3,5-dimethoxy-phenyl)-2-oxo-2-phenyl-ethoxy]-phosphanyloxy}-5-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-furan-2-yl]-2-oxo-1,2-dihydro-pyrimidin-4-yl}-carbamic acid allyl ester 
• 1054620-47-1 {1-[(2R,4S,5R)-4-{Allyloxy-[1-(3,5-dimethoxy-phenyl)-2-oxo-2-phenyl-ethoxy]-phosphanyloxy}-5-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-furan-2-yl]-5-methyl-2-oxo-1,2-dihydro-pyrimidin-4-yl}-carbamic acid allyl ester 
• 1053633-09-2 [1-((2R,4S,5R)-5-(tert-Butyl-diphenyl-silanyloxymethyl)-4-{(2-cyano-ethoxy)-[1-(3,5-dimethoxy-phenyl)-2-oxo-2-phenyl-ethoxy]-phosphanyloxy}-tetrahydro-furan-2-yl)-2-oxo-1,2-dihydro-pyrimidin-4-yl]-carbamic acid allyl ester 
• 1055028-96-0 [1-((2R,4S,5R)-5-(tert-Butyl-diphenyl-silanyloxymethyl)-4-{(2-cyano-ethoxy)-[1-(3,5-dimethoxy-phenyl)-2-oxo-2-phenyl-ethoxy]-phosphanyloxy}-tetrahydro-furan-2-yl)-5-methyl-2-oxo-1,2-dihydro-pyrimidin-4-yl]-carbamic acid allyl ester 
• 1054608-85-3 {6-Allyloxy-9-[(2R,4S,5R)-4-{allyloxy-[1-(3,5-dimethoxy-phenyl)-2-oxo-2-phenyl-ethoxy]-phosphanyloxy}-5-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-furan-2-yl]-9H-purin-2-yl}-carbamic acid allyl ester 
• 1053262-15-9 [9-((2R,4S,5R)-5-(tert-Butyl-diphenyl-silanyloxymethyl)-4-{(2-cyano-ethoxy)-[1-(3,5-dimethoxy-phenyl)-2-oxo-2-phenyl-ethoxy]-phosphanyloxy}-tetrahydro-furan-2-yl)-9H-purin-6-yl]-carbamic acid allyl ester 
• 1053648-85-3 [6-Allyloxy-9-((2R,4S,5R)-5-(tert-butyl-diphenyl-silanyloxymethyl)-4-{(2-cyano-ethoxy)-[1-(3,5-dimethoxy-phenyl)-2-oxo-2-phenyl-ethoxy]-phosphanyloxy}-tetrahydro-furan-2-yl)-9H-purin-2-yl]-carbamic acid allyl ester 
• 169309-14-2 Carbonic acid 1-(3,5-dimethoxy-phenyl)-2-oxo-2-phenyl-ethyl ester 4-nitro-phenyl ester 
• 169309-12-0 Cyclohexyl-carbamic acid 1-(3,5-dimethoxy-phenyl)-2-oxo-2-phenyl-ethyl ester 
• 188924-61-0 (3',5'-dimethoxyphenyl)phenylethane-1,2-dione 
• 357194-61-7 dodecanoic acid 1-(3,5-dimethoxyphenyl)-2-oxo-2-phenylethyl ester 

Relevant articles and documents

Photoinduced Release of a Chemical Fuel for Acid–Base-Operated Molecular Machines

Back and forth motions of the acid–base-operated molecular switch 1 are photo-controlled by irradiation of a solution, which also contains the photolabile pre-fuel 4. The photo-stimulated deprotection of the pre-fuel produces controlled amounts of acid 2,

A time-resolved spectroscopic study of the bichromophoric phototrigger 3',5'-dimethoxybenzoin diethyl phosphate: Interaction between the two chromophores determines the reaction pathway

3',5'-Dimethoxybenzoin (DMB) is a bichromophoric system that has widespread application as a highly efficient photoremovable protecting group (PRPG) for the release of diverse functional groups. The photodeprotection of DMB phototriggers is remarkably cle

Wavelength-controlled orthogonal photolysis of protecting groups

The selective control of a chemical process by the use of an electromagnetic wave has been a challenging goal for several decades. In this article, we describe for the first time the use of a monochromatic light beam to differentiate two different reactive centers. A direct application of this concept is found in the chemistry of protecting groups. Two different photolabile protecting groups were tuned to be responsive to a specific wavelength (e.g., 254 or 420 nm). Using derivatives of the 2-nitroveratryl fragment (such as 10, sensitive at 420 nm) and 3′,5′-dimethoxybenzoin fragment (such as 4, sensitive at 254 nm), it was shown that energy transfer phenomena did not erode the selectivity. Both the inter- and the intramolecular cases were studied and showed selectivities within the synthetically useful range. Hence, we could replace the traditional chemical orthogonality by a chromatic orthogonality.