349537-83-3Relevant articles and documents
Asymmetric hydrogenation of enamides with Rh-BisP* and Rh-MiniPHOs catalysts. Scope, limitations, and mechanism
Gridnev,Yasutake,Higashi,Imamoto
, p. 5268 - 5276 (2007/10/03)
The asymmetric hydrogenation of aryl- and alkyl-substituted enamides catalyzed by Rh-BisP* complex affords optically active amides with very high ee values. The Rh-MiniPHOS catalyst gives somewhat less satisfactory results. Hydrogenation of the aryl-subst