35022-15-2Relevant articles and documents
Triphenylamine/4,4′-Dimethoxytriphenylamine-Functionalized Thieno[3,2-b]thiophene Fluorophores with a High Quantum Efficiency: Synthesis and Photophysical Properties
Isci, Recep,Unal, Melis,Kucukcakir, Gizem,Gurbuz, Naime A.,Gorkem, Sultan F.,Ozturk, Turan
, p. 13309 - 13319 (2021/12/06)
A wide series of 10 new triphenylamine (TPA)/4,4′-dimethoxytriphenylamine (TPA(OMe)2)-functionalized thieno[3,2-b]thiophene (TT) fluorophores,4a-eand5a-e, bearing different electron-donating and electron-withdrawing substituents (-PhCN, -PhF, -
Oxidative biaryl coupling of thiophenes and thiazoles with arylboronic acids through palladium catalysis: Otherwise difficult C4-selective C-H arylation enabled by boronic acids
Kirchberg, Sylvia,Tani, Satoshi,Ueda, Kirika,Yamaguchi, Junichiro,Studer, Armido,Itami, Kenichiro
supporting information; experimental part, p. 2387 - 2391 (2011/04/21)
(Chemical Equation Presented) It adds up to 4! Thiophenes and thiazoles can be arylated in the 4- rather than the expected 5-position in a new C-H functionalization reaction (see scheme; TEMPO: 2,2,6,6-tetramethylpiperidine-N- oxyl). The boronic acid proved to be the key to achieving the otherwise difficult C4 selectivity. The method was applied to a concise synthesis of a key pharmacological structure with potential for treatment of Alzheimers disease.