354-92-7Relevant articles and documents
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Barber et al.
, p. 4241 (1951)
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Buerger,Pawelke
, p. 559 (1979)
LASER-INDUCED DECOMPOSITION OF HEPTAFLUORO-2-IODOPROPANE
Pola, Josef,Horak, Milan
, p. 121 - 124 (2007/10/02)
CO2 laser-induced homogeneous decomposition of i-C3F7I yields a variety of perfluorinated compounds, which are suggested to be formed by recombinations of carbenes and radicals generated upon the cleavage of the C-1 bond and the fragmentation of the i-C3F7 radical.The decomposition of i-C3F7I in the presence of ethene leads mainly to the formation of (i-C3F7CH2)2 and i-C3F7(CH2)2I.
Synthesis of Functional Perfluorinated Resins, Branched Perfluorinated Ethers and Perfluoroalkanoyl Fluorides
Huang, Hsu-Nan,Lagow, Richard J.
, p. 871 - 875 (2007/10/02)
Functional-group-containing perfluorinated resins have been prepared by carefully controlled direct fluorination of poly-(3-methyloxetane-3-methanol).Branched perfluorinated ethers such as bis(perfluoroneopentyl) ether and perfluoro-(2,2-dimethylbutyl methyl ether) have also been synthesized by direct fluorination of alkanols.The by-products, perfluoroalkanoyl fluorides, are useful intermediates.
THE FLUORINATION OF BUTANE OVER COBALT TRIFLUORIDE
Burdon, James,Ezmirly, Saleh T.,Huckerby, Thomas N.
, p. 283 - 318 (2007/10/02)
The fluorination of butane over cobalt trifluoride has given a complex mixture of partially fluorinated compounds: 51 of these have been identified, comprising over 99percent of the products.Most were polyfluor-butanes but 1-2percent were polyfluoro-2-methylpropanes.The reaction has no synthetic utility.There was some selectivity in the fluorination: secondary C-H was convertart byed into C-F more easily then primary, and the ease of replacement of a particular H was reduced by geminal vicinal fluorines.A computer model of the fluorination was only partially successful, perhaps because the fluorination proceeded in part by simple F for H replacement and in part via alkenes: the model only allowed for the former.