35416-67-2

Basic information

• Product Name: diethyl 2,7-diethoxycarbonyl-4-octenedioate
• CAS NO: 35416-67-2
• Molecular Weight: 372.416
• Mol File: 35416-67-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: diethyl 2,7-diethoxycarbonyl-4-octenedioate(CAS DataBase Reference)
• NIST Chemistry Reference: diethyl 2,7-diethoxycarbonyl-4-octenedioate(35416-67-2)
• EPA Substance Registry System: diethyl 2,7-diethoxycarbonyl-4-octenedioate(35416-67-2)

Safety Data

• Hazardous Substances Data: 35416-67-2(Hazardous Substances Data)

Upstream product

• 6974-12-5 1,4-dibromo-2-butene 
• 105-53-3 diethyl malonate 
• 764-41-0 1,4-dichloro-2-butene 
• 996-82-7 sodium diethylmalonate 
• 64-17-5 ethanol 
• 821-06-7 (E)-1,4-dibromobutene 

Relevant articles and documents

ALKYLATION OF CH ACIDS IN THE PRESENCE OF POTASSIUM CARBONATE. II. ALKYLATION OF ACETYLACETONE; ACETOACETIC ESTER; AND MALONIC ESTER WITH 1,4-DIHALOGENO-2-BUTENES

A convenient method was developed for the synthesis of derivatives of vinylcyclopropane and vinyldihydrofurane by the cycloalkylation of acetylacetone, acetoacetic ester, and malonic ester with 1,4-dihalogeno-2-butenes in the presence of potassium carbonate.The reaction of acetylacetone and acetoacetic ester with 1,4-dibromo-2,3-dimethyl-2-butene is regiospecific with the formation of the products from intramolecular O-alkylation.The isomerization of the 1-substituted 1-acyl-2-vinylcyclopropanes with the corresponding dihydrofurans is accelerated in the presence of catalytic amounts of cuprous chloride.