356056-15-0

Basic information

• Product Name: N-[4-(1H,1H,2H,2H-PERFLUORODECYL)BENZYLOXYCARBONYLOXY]SUCCINIMIDE
• Synonyms: N-[4-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-HEPTADECAFLUORODECYL) BENZYLOXYCARBONYLOXY]SUCCINIMIDE;N-[4-(1H,1H,2H,2H-PERFLUORODECYL)BENZYLOXYCARBONYLOXY]SUCCINIMIDE;(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-HEPTADECAFLUORODECYL)DIISOPROPYLSILANE;DIISOPROPYL(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-HEPTADECAFLUORODECYL)SILANE;DIISOPROPYL(1H,1H,2H,2H-PERFLUORODECYL)SILANE;(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecyl)diisopropylsilane, Diisopropyl(1H,1H,2H,2H-perfluorodecyl)silane;Diisopropyl(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)silane >=95%
• CAS NO: 356056-15-0
• Molecular Formula: C₁₆H₁₉F₁₇Si
• Molecular Weight: 562.38
• Mol File: 356056-15-0.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 280.785°C at 760 mmHg
• Flash Point: >110℃
• Appearance: /
• Density: 1.385 g/mL at 25 °C
• Vapor Pressure: 0.006mmHg at 25°C
• Refractive Index: n20/D1.357
• Storage Temp.: −20°C
• CAS DataBase Reference: N-[4-(1H,1H,2H,2H-PERFLUORODECYL)BENZYLOXYCARBONYLOXY]SUCCINIMIDE(CAS DataBase Reference)
• NIST Chemistry Reference: N-[4-(1H,1H,2H,2H-PERFLUORODECYL)BENZYLOXYCARBONYLOXY]SUCCINIMIDE(356056-15-0)
• EPA Substance Registry System: N-[4-(1H,1H,2H,2H-PERFLUORODECYL)BENZYLOXYCARBONYLOXY]SUCCINIMIDE(356056-15-0)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26
• WGK Germany: 3
• F: 10-21
• Hazardous Substances Data: 356056-15-0(Hazardous Substances Data)

Usage

InChI:InChI=1/C16H19F17Si/c1-7(2)34(8(3)4)6-5-9(17,18)10(19,20)11(21,22)12(23,24)13(25,26)14(27,28)15(29,30)16(31,32)33/h7-8,34H,5-6H2,1-4H3

Upstream product

• 2043-53-0 2-(n-perfluorooctyl)ethyl iodide 
• 374928-84-4 diisopropyl-1H,1H,2H,2H-perfluorodecylsilyl 2-(2-naphthyl)ethyl ether 
• 2227-29-4 chlorodiisopropylsilane 

Downstream Products

• 374928-86-6 diisopropyl-1H,1H,2H,2H-perfluorodecylsilyl cinnamyl ether 

Relevant articles and documents

Cap-and-tag solid phase oligosaccharide synthesis

(Chemical Equation Presented) A new "cap-and-tag" strategy is applied to solid phase oligosaccharide synthesis. Acetyl-capping and fluorous-tagging allowed for the facile separation of the desired F-tagged oligosaccharide from the acetyl-capped deletion sequences using fluorous solid phase extraction. To illustrate this approach, a protected Glc-β-(1→6) -Man-α-(1→6)-Glc-β-1→pentenyl trisaccharide was synthesized.

Reaction and separation methods

A method of separating compounds that includes the steps of: tagging at least a first organic compound with a first tagging moiety to result in a first tagged compound; tagging at least a second organic compound with a second tagging moiety different from

Fluorous triphasic reactions: Transportative deprotection of fluorous silyl ethers with concomitant purification [11]

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