3585-90-8

Basic information

• Product Name: COPPER(II) IONOPHORE II
• Synonyms: COPPER(II) IONOPHORE II;N-Phenyl-a-(4-nitrophenyl)nitrone;N-Phenyl-α-(4-nitrophenyl)nitrone;α-(4-Nitrophenyl)-N-phenylnitrone
• CAS NO: 3585-90-8
• Molecular Formula: C₁₃H₁₀N₂O₃
• Molecular Weight: 242.2301
• Mol File: 3585-90-8.mol
• Article Data: 15

Chemical Properties

• Appearance: /
• Storage Temp.: 2-8°C
• CAS DataBase Reference: COPPER(II) IONOPHORE II(CAS DataBase Reference)
• NIST Chemistry Reference: COPPER(II) IONOPHORE II(3585-90-8)
• EPA Substance Registry System: COPPER(II) IONOPHORE II(3585-90-8)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26
• Hazardous Substances Data: 3585-90-8(Hazardous Substances Data)

Upstream product

• 586-96-9 Nitrosobenzene 
• 100-11-8 1-bromomethyl-4-nitro-benzene 
• 785-80-8 p-nitrobenzylideneaniline 
• 555-16-8 4-nitrobenzaldehdye 
• 98-95-3 nitrobenzene 
• 100-65-2 N-Phenylhydroxylamine 

Downstream Products

• 26928-17-6 ethyl 2-fluoro-3-(4-nitrophenyl)-(E)-propenoate 
• 26928-18-7 ethyl 2-fluoro-3-(4-nitrophenyl)-(Z)-propenoate 
• 87289-98-3 [(3R,4R,5S)-4-Benzenesulfonyl-3-(4-nitro-phenyl)-2-phenyl-isoxazolidin-5-yl]-phenyl-methanone 
• 87289-96-1 (3S,4S,5R)-4-Benzenesulfonyl-5-methyl-3-(4-nitro-phenyl)-2-phenyl-isoxazolidine 
• 69374-59-0 3,6-bis-(4-nitro-phenyl)-1,4-diphenyl-1,4-dihydro-[1,2,4,5]tetrazine 
• 71475-56-4 3-(4-nitro-phenyl)-2,5,7-triphenyl-2,3,5,7a-tetrahydro-[1,2,3]diazarsolo[3,4-d][1,2,4]oxazarsole 
• 1028342-25-7 (3R,5R)-5-ethoxy-3-(4-nitrophenyl)-2-phenylisoxazolidine 
• 1018741-03-1 C₇₀H₇₂N₄O₁₀ 
• 89539-45-7 C₁₇H₁₃N₃O₅ 
• 3460-11-5 4-nitrobenzanilide 

Relevant articles and documents

Single-Step Approach toward Nitrones via Pyridinium Ylides: The DMAP-Catalyzed Reaction of Benzyl Halides with Nitrosoarenes

A single-step approach is reported for the preparation of nitrones from benzyl halides and nitrosoarenes via pyridinium ylides, utilizing 4-dimethylaminopyridine (DMAP) catalyst and mild reaction conditions (Li2CO3, dimethylacetamide, and room temperature). The reaction provides both keto-and aldonitrones in high yields with a wide scope for benzyl halides and nitrosoarenes. In the same reaction system, 2-methyl-2-nitrosopropane, which does not have an aryl group, also affords the corresponding N-tert-butyl nitrones from primary benzyl bromides that have an electron-withdrawing group. As an application of the reaction, methyl 2-bromo-2-phenylacetate was used to prepare the corresponding isoxazolidine by a sequential one-pot synthesis.

Enantioselective 1,3-dipolar cycloaddition of nitrones with ethyl vinyl ether: The difference between Bronsted and Lewis acid catalysis

(Chemical Equation Presented) Bronsted and Lewis face off: A new chiral N-triflyl phosphoramide is used for asymmetric 1,3-dipolar cycloaddition of diaryl nitrones to ethyl vinyl ether to give the endo products in up to 93% ee (see scheme; Tf = trifluoromethanesulfonyl; Ad = adamantyl). The structure of the chiral phosphoramide was confirmed by X-ray crystallographic analysis.

Iron and manganese (III) - Porphyrins as new applicable catalysts for selective oxidation of imines with urea-hydrogen peroxide

A variety of imines were oxidised with urea-hydrogen peroxide using iron(III) and manganese (III)- tetraphenylporphyrins [Fe(TPP)Cl], [Mn(TPP)Cl] and manganese (III)-octabromotetraphenyl porphyrin [Mn(TPPBr8)Cl] as catalysts. Experimental resul