36429-12-6Relevant articles and documents
DESTRUCTIVE NITRATION OF ALIPHATIC γ,γ-DINITRO KETONES AND ALDEHYDES. SYNTHESIS OF HALOGENOPENTANITROETHANES AND 1,1,1,2,2-PENTANITROPROPANE
Tselinskii, I. V.,Shokhor, I. N.,Bagal, L. I.
, p. 1039 - 1041 (2007/10/02)
The nitration of 2,2-dinitro-2-R-5-pentanones ( R = H, Cl, Br ) with a mixture of nitric and sulfuric acids leads to R'-pentanitroethanes ( R' = NO2, Cl, Br ). 1,1,1,2,2-Pentanitropropane was obtained similarly with 56-58percent yields during the nitration of 2,2-dinitro-5-hexanone, 2,2-dinitro-5-phenyl-5-pentanone, and 4,4-dinitropentanal.
