36881-00-2Relevant articles and documents
Highly efficient acetalization of carbonyl compounds catalyzed by anilin-aldehyde resin salts
Tanemura, Kiyoshi,Suzuki, Tsuneo
supporting information, p. 797 - 799 (2015/06/22)
A mild procedures for the syntheses of ethylene acetals and dimethyl acetals from the corresponding aldehydes and ketones catalyzed by 1mol% of anilinealdehyde resin salts are described. This method is also useful for the synthesis of dimethyl acetals of diaryl ketones.
Regioselective transformation of alkynes into cyclic acetals and thioacetals with a gold(I) catalyst: comparison with Br?nsted acid catalysts
Santos, Laura L.,Ruiz, Violeta R.,Sabater, Maria J.,Corma, Avelino
, p. 7902 - 7909 (2008/12/21)
Au(I) catalyzes the transformation of alkynes into cyclic acetals and thioacetals at much higher rate than Br?nsted acids. The reaction appears to be general for a range of alkynes and diols or dithiols, which are efficiently transformed with high selectivities. One of the salient features of this reaction process is the high reactivity of the enol ether or enol thioether intermediates, which undergo a rapid isomerization reaction to afford the cyclic acetals or thioacetals, so that isolation or subsequent activation processes are not required. This type of reactions allows us to synthesize a series of fragrances.
Palladium-catalysed direct regioselective synthesis of cyclic ketals from electron-rich olefins and aryl bromides in ionic liquids
Hyder, Zeynab,Mo, Jun,Xiao, Jianliang
, p. 1699 - 1704 (2007/10/03)
The Heck reaction comprises one of the most important carbon-carbon coupling reactions in organic synthesis. The popularity of the reaction is attributable to the broad availability of aryl halides and to the tolerance of the reaction for a wide variety o