37542-28-2

Basic information

• Product Name: methyl 2-(4-chlorophenyl)-2-oxoacetate
• Synonyms: methyl 2-(4-chlorophenyl)-2-oxoacetate
• CAS NO: 37542-28-2
• Molecular Weight: 198.606
• Mol File: 37542-28-2.mol
• Article Data: 47

Chemical Properties

• CAS DataBase Reference: methyl 2-(4-chlorophenyl)-2-oxoacetate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2-(4-chlorophenyl)-2-oxoacetate(37542-28-2)
• EPA Substance Registry System: methyl 2-(4-chlorophenyl)-2-oxoacetate(37542-28-2)

Safety Data

• Hazardous Substances Data: 37542-28-2(Hazardous Substances Data)

Upstream product

• 32174-34-8 methyl 4-chloromandelate 
• 67-56-1 methanol 
• 27704-37-6 2,2,2-trichloro-1-(4-chlorophenyl)ethanone 
• 52449-43-1 (4-chloro-phenyl)-acetic acid methyl ester 
• 124-41-4 sodium methylate 
• 5781-53-3 monomethyl oxalyl chloride 
• 89523-62-6 (4-chlorophenyl)zinc(II) chloride 
• 93961-29-6 methyl 2-(4-chlorophenyl)-2-diazoacetate 
• 1972-28-7 diethylazodicarboxylate 
• 13014-48-7 4-chlorobenzoyl cyanide 
• 60-29-7 diethyl ether 
• 7732-18-5 water 
• 536-38-9 4-chlorobenzoylmethyl bromide 
• 106-39-8 bromochlorobenzene 

Downstream Products

• 63096-36-6 (4-chloro-phenyl)-hydroxy-acetic acid methyl ester 
• 32174-34-8 (4-chloro-phenyl)-hydroxy-acetic acid methyl ester 
• 248582-67-4 methyl (Z)-O-methyloximino-2-(4-chloro)phenylacetate 
• 7099-88-9 4-chlorophenylglyoxylic acid 
• 959161-42-3 S-t-butyl (4-chlorophenyl)-hydroxythioacetate 
• 959161-60-5 S-t-butyl (4-chlorophenyl)-oxo-thioacetate 
• 104132-79-8 2-(4-chlorophenyl)-2-oxoacetyl chloride 
• 76496-63-4 (S)-4-chloro-α-hydroxy-benzeneacetic acid 
• 380610-20-8 2-(chlorophenyl)-3,3-dichloroacrylic acid methyl ester 
• 32174-34-8 methyl 4-chloromandelate 
• 60300-84-7 methyl α-benzyloxyphenylacetate 
• 1086108-75-9 (Z)-methyl 2-(4-chlorophenyl)-2-(4-methoxyphenylimino)acetate 

Relevant articles and documents

Tris(pentafluorophenyl)borane-Catalyzed Oxygen Insertion Reaction of α-Diazoesters (α-Diazoamides) with Dimethyl Sulfoxide

A tris(pentafluorophenyl)borane-catalyzed oxidation reaction of α-diazoesters (α-diazo amides) with dimethyl sulfoxide has been developed. The reaction proceeds under metal free conditions to afford a series α-ketoesters and α-ketoamides. The synthetic utility of this protocol is demonstrated through synthetic transformations and scaled-up synthesis. (Figure presented.).

Photoinduced Diverse Reactivity of Diazo Compounds with Nitrosoarenes

A diverse reactivity of diazo compounds with nitrosoarene in an oxygen-transfer process and a formal [2 + 2] cycloaddition is reported. Nitosoarene has been exploited as a mild oxygen source to oxidize an in situ generated carbene intermediate under visible-light irradiation. UV-light-mediated in situ generated ketenes react with nitosoarenes to deliver oxazetidine derivatives. These operationally simple processes exemplify a transition-metal-free and catalyst-free protocol to give structurally diverse α-ketoesters or oxazetidines.

[Fe(bpy)3]2+-based porous organic polymers with boosted photocatalytic activity for recyclable organic transformations

Three rigid metal porous organic polymers (POPs) based on an iron(ii) complex are prepared from the condensation reactions of an octahedral [Fe(bpy)3]2+-cored hexaaldehyde and three rod-like aromatic diamines. The POPs have been studied as the first series of earth-abundant metal complex-connected photocatalysts for heterogeneous visible light-driven oxidation of benzyl halides and enantioselective α-alkylation of aldehydes. Both yields and enantioselectivities of the reactions catalyzed by one of the POPs, which possesses the largest porosity, rival or even surpass those of the reactions homogeneously catalyzed by control [Fe(bpy)3]2+complexes. Moreover, POP catalysts are highly stable and exhibit a considerable activity after recycling 10 times.