38430-69-2

Basic information

• Product Name: O²,O³,O⁴,O⁶-Tetraacetyl-O¹-benzoyl-β-D-glucopyranose
• Synonyms: O²,O³,O⁴,O⁶-Tetraacetyl-O¹-benzoyl-β-D-glucopyranose
• CAS NO: 38430-69-2
• Molecular Weight: 452.415
• Mol File: 38430-69-2.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: O²,O³,O⁴,O⁶-Tetraacetyl-O¹-benzoyl-β-D-glucopyranose(CAS DataBase Reference)
• NIST Chemistry Reference: O²,O³,O⁴,O⁶-Tetraacetyl-O¹-benzoyl-β-D-glucopyranose(38430-69-2)
• EPA Substance Registry System: O²,O³,O⁴,O⁶-Tetraacetyl-O¹-benzoyl-β-D-glucopyranose(38430-69-2)

Safety Data

• Hazardous Substances Data: 38430-69-2(Hazardous Substances Data)

Upstream product

• 3947-62-4 2,3,4,6-tetra-O-acetyl-β-D-glucopyranose 
• 65-85-0 benzoic acid 
• 407-25-0 trifluoroacetic anhydride 
• 3947-62-4 2,3,4,6-tetra-O-acetyl-D-mannopyranose 
• 5207-08-9 bis(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)disulfide 
• 19879-84-6 tetraacetyl thioglucose 
• 83-87-4 D-glucose pentaacetate 
• 572-09-8 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide 
• 74808-10-9 O-(2,3,4,6-Tetra-O-acetyl-α-D-glucopyranosyl)trichloroacetimidate 
• 2873-29-2 D-glucal triacetate 
• 93-59-4 Perbenzoic acid 
• 3947-62-4 2,3,4,6-tetraacetylglucose 
• 108-24-7 acetic anhydride 
• 439-03-2 2,3,4,6-tetra-O-acetyl-1-fluoro-α-D-glucopyranose 

Relevant articles and documents

Improved synthesis of 1-O-acyl-β-D-glucopyranose tetraacetates

An improved synthesis of 1-O-acyl glucosyl esters that avoids the use of expensive Ag reagents as well as the hydrolysis of unstable glucosyl bromides is reported. Notably, β-configuration products were obtained exclusively in good yields.

-

-

Synthesis of some monosaccharide-related ester derivatives as insecticidal and acaricidal agents

To develop natural-product-based pesticidal agents, a series of monosaccharide-related ester derivatives (17a–q and 18a–f), glucose (xylose)-piperic acid/piperic acid-like conjugates, were synthesized. Three-dimensional structures of compounds 17b, 17g, 17h, and 17n were unambiguously determined by single-crystal X-ray diffraction. Especially compounds 18e and 18f exhibited the most potent insecticidal and acaricidal activities against Mythimna separata and Tetranychus cinnabarinus. Their structure-activity relationships were also discussed.

Polyvinyl trisulfonate ethylamine based solid acid catalyst for the efficient glycosylation of sugars under solvent free conditions

Heterogeneous Bronsted solid acid catalysts have the potential to decrease the environmental impact related to chemical production. Herein, we have synthesized polyvinyl bound trisulfonate ethylamine chloride (PV-THEAC) and polyvinyl bound disulfonate ethylamine (PV-DSEA) as Bronsted solid acid catalysts which exhibited effective catalytic activity for acid catalyzed glycosylation reactions with sugar derivatives. In particular, 0.3 equiv. of the PV-THEAC catalyst was found to be the most efficient and a reusable catalyst for glycosylation reactions. A high density of the trisulfonic group (-OSO3H) contributed to the excellent catalytic activity during glycosylation. Moreover, glycosylation reactions with d-mannose, d-xylose and d-glucose have been studied with alcohol. Remarkable acceleration of the glycosylation reaction using a glycosyltrichloroacetimidate donor was obtained with the selective production of β-glycoside.