3968-10-3Relevant articles and documents
A microwave-assisted approach to N-(2-nitrophenyl)benzenesulfonamides that enhanced peroxidase activity in response to excess cadmium
Huang, Zhi-You,Liu, Min,Mao, Yi-Jun,Chen, Yu-De,Wang, Yan-Ping,Liu, Chong
supporting information, p. 626 - 629 (2019/02/01)
A facile and efficient approach to N-(2-nitrophenyl) benzenesulfonamides was developed under microwave irradiation. A series of pyrabactin analogues containing nitrophenyl scaffold was obtained in excellent yields. In addition, the method was pretty suitable to prepare flusulfamide. Significantly, the 3ae could enhance POD activity in response to heavy metal stress.
Copper-Catalyzed Direct Nitration on Aryl C-H Bonds by Concomitant Azidation-Oxidation with TMS Azide and TBHP under Aerobic Conditions
Vinayak, Botla,Chandrasekharam, Malapaka
, p. 3528 - 3531 (2017/07/17)
An unprecedented copper-catalyzed in situ azidation-oxidation for the nitration of anilides and sulfonamides has been developed by direct CAr-H functionalization. This novel and efficient nitration protocol is achieved employing TMSN3 and TBHP without the exclusion of air or moisture. The synthetic applications of the 2-nitroanilides have been explored.
Chemoselective nitration of aromatic sulfonamides with tert-butyl nitrite
Kilpatrick, Brenden,Heller, Markus,Arns, Steve
, p. 514 - 516 (2013/02/25)
A methodology for the efficient conversion of aromatic sulfonamides into their mono-nitro derivatives using tert-butyl nitrite is reported. The reaction exhibits a high degree of chemoselectivity for sulfonamide functionalized aryl systems, even in the presence of other sensitive or potentially reactive functionalities.