40105-57-5

Basic information

• Product Name: tetra-n-butylammonium (2E)-3-phenylprop-2-enoate
• Synonyms: tetra-n-butylammonium (2E)-3-phenylprop-2-enoate
• CAS NO: 40105-57-5
• Molecular Weight: 389.622
• Mol File: 40105-57-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: tetra-n-butylammonium (2E)-3-phenylprop-2-enoate(CAS DataBase Reference)
• NIST Chemistry Reference: tetra-n-butylammonium (2E)-3-phenylprop-2-enoate(40105-57-5)
• EPA Substance Registry System: tetra-n-butylammonium (2E)-3-phenylprop-2-enoate(40105-57-5)

Safety Data

• Hazardous Substances Data: 40105-57-5(Hazardous Substances Data)

Upstream product

• 140-10-3 (E)-3-phenylacrylic acid 
• 2052-49-5 tetra(n-butyl)ammonium hydroxide 
• 32503-27-8 tetra(n-butyl)ammonium hydrogensulfate 

Downstream Products

• 616-75-1 2-benzylmalonic acid 

Relevant articles and documents

The: Trans / cis photoisomerization in hydrogen bonded complexes with stability controlled by substituent effects: 3-(6-aminopyridin-3-yl)acrylate case study

The association of aminopyridine-based acrylic acid and its salt was studied by NMR titration experiments. The AA (acceptor, acceptor) hydrogen-bonding pattern present in the salt forms a complex readily with a DD (donor, donor) hydrogen-bonding pattern of the substituted ureas even in polar and competitive environment. The double carbon-carbon bond in the acrylic acid derivative is subjected to photoisomerization. This is dependent on the association with substituted urea derivatives. The substituent in ureas influences the trans/cis isomerization kinetics and position of the photostationary state. Two mechanisms that influence the photoisomerization were proposed. To the best of our knowledge, the trans/cis photoisomerization influenced by the substituent in such a hydrogen-bonding pattern has not observed previously. It was shown that interaction with urea derivatives causes lowering of the trans-to-cis photoreaction rates.