426265-84-1Relevant articles and documents
Nickel-catalyzed silaboration of small-ring vinylcycloalkanes: Regio- and stereoselective (E)-allylsilane formation via C-C bond cleavage
Suginome, Michinori,Matsuda, Takanori,Yoshimoto, Takayo,Ito, Yoshihiko
, p. 1537 - 1539 (2008/10/08)
The nickel-catalyzed silaboration of small-ring vinylcycloalkanes was analyzed. These reactions provided (ω-borylalkyl)-substituted allylsilanes in a highly regio- and stereoselective manner. The results highlight the relatively unexplored bis- and hydrometalation chemistry of vinylcycloalkanes.