4286-85-5

Basic information

• Product Name: Benzene, 1,1'-(3-butenylidene)bis-
• CAS NO: 4286-85-5
• Molecular Formula: C16H16
• Molecular Weight: 208.303
• Mol File: 4286-85-5.mol
• Article Data: 67

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-(3-butenylidene)bis-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-(3-butenylidene)bis-(4286-85-5)
• EPA Substance Registry System: Benzene, 1,1'-(3-butenylidene)bis-(4286-85-5)

Safety Data

• Hazardous Substances Data: 4286-85-5(Hazardous Substances Data)

Upstream product

• 10060-17-0 (diphenylmethyl)potassium 
• 107-05-1 3-chloroprop-1-ene 
• 91-01-0 1,1-Diphenylmethanol 
• 762-72-1 allyl-trimethyl-silane 
• 101-81-5 Diphenylmethane 
• 106-95-6 allyl bromide 
• 100-52-7 benzaldehyde 
• 100-58-3 phenylmagnesium bromide 
• 881-42-5 diphenylmethyllithium 
• 119-61-9 benzophenone 
• 4028-23-3 Allylchlorodimethylsilane 
• 501-65-5 diphenyl acetylene 
• 954-67-6 benzhydryl acetate 
• 25152-47-0 2,2-diphenyl-1-methylenecyclopropane 

Downstream Products

• 4286-87-7 but-3-yne-1,1-diyldibenzene 
• 791739-82-7 4-(2,2-diphenylethyl-1) 2-amino[1H]4,5-dihydro imidazole 
• 93010-27-6 but-2-ene-1,1-diyldibenzene 
• 1726-14-3 1,1-diphenyl-1-butene 
• 23434-73-3 5,5-diphenylpentanoic acid 
• 54766-52-8 4,4-diphenyl-1,2-epoxybutane 
• 85316-45-6 (4,4-Diphenylbutyl) pentamethyl disiloxane 
• 4279-99-6 (1,1-Dimethyl-5,5-diphenyl-pent-2-ynyl)-dimethyl-amine 
• 719-79-9 1,1-diphenylbutane 
• 61323-44-2 5-Chlor-4,4-diphenyl-1-penten 

Relevant articles and documents

Titanocene(II)-promoted stereoselective alkenylation utilizing (Z)-alkenyl sulfones

(Chemical Equation Presented) The stereoselective alkenylation of unsaturated compounds by means of a (Z)-alkenyl sulfone-titanocene-(II) system is described. Treatment of alkynes and (Z)-alkenyl methyl sulfones with the titanocene(II) reagent Cp2Ti[P(OEt)3]2 produced conjugated dienes. This alkenylation system is also applicable to polar C=O bonds; the simple mixing of carbonyl compounds, (Z)-alkenyl methyl sulfones, and the titanocene-(II) reagent formed allylic alcohols. The advantages of alkenylation are that it requires no prepreparation of the alkenylmetal reagent and that it proceeds with complete stereoselectivity.

Direct AlCl3-catalyzed transformation of benzyl THP ethers and allyl benzyl ethers

THP and allyl groups are frequently used for the protection of alcohols. In this study, novel direct transformations of benzyl THP ethers and allyl benzyl ethers, protected forms of alcohols, are reported. TMSN3 and AlCl3 were employ

Arylboronic Acid Catalyzed C-Alkylation and Allylation Reactions Using Benzylic Alcohols

The arylboronic acid catalyzed dehydrative C-alkylation of 1,3-diketones and 1,3-ketoesters using secondary benzylic alcohols as the electrophile is reported, forming new C-C bonds (19 examples, up to 98% yield) with the release of water as the only byproduct. The process is also applicable to the allylation of benzylic alcohols using allyltrimethylsilane as the nucleophile (12 examples, up to 96% yield).