42917-48-6

Basic information

• Product Name: (4-fluorophenyl)(4-(trifluoromethyl)phenyl)sulfane
• Synonyms: (4-fluorophenyl)(4-(trifluoromethyl)phenyl)sulfane
• CAS NO: 42917-48-6
• Molecular Weight: 272.266
• Mol File: 42917-48-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (4-fluorophenyl)(4-(trifluoromethyl)phenyl)sulfane(CAS DataBase Reference)
• NIST Chemistry Reference: (4-fluorophenyl)(4-(trifluoromethyl)phenyl)sulfane(42917-48-6)
• EPA Substance Registry System: (4-fluorophenyl)(4-(trifluoromethyl)phenyl)sulfane(42917-48-6)

Safety Data

• Hazardous Substances Data: 42917-48-6(Hazardous Substances Data)

Upstream product

• 371-42-6 4-Fluorothiophenol 
• 329-15-7 4-trifluoromethyl-phenyl acetyl chloride 
• 2927-96-0 4-substituted phelylthiol benzoate 
• 1535-35-9 4-fluorobenzenesulphenyl chloride 
• 402-51-7 4-(trifluoromethyl)phenylmagnesium bromide 

Downstream Products

• 126799-55-1 1-Methyl-4-[4-(4-trifluoromethyl-phenylsulfanyl)-phenoxy]-piperidine 

Relevant articles and documents

Pd-Catalyzed Double-Decarbonylative Aryl Sulfide Synthesis through Aryl Exchange between Amides and Thioesters

We report the palladium-catalyzed double-decarbonylative synthesis of aryl thioethers by an aryl exchange reaction between amides and thioesters. In this method, amides serve as aryl donors and thioesters are sulfide donors, enabling the synthesis of valuable aryl sulfides. The use of Pd/Xantphos without any additives has been identified as the catalytic system promoting the aryl exchange by C(O)-N/C(O)-S cleavages. The method is amenable to a wide variety of amides and sulfides.