43052-01-3

Basic information

• Product Name: Oxaziridine, 2-(1,1-dimethylethyl)-3-(4-methoxyphenyl)-
• CAS NO: 43052-01-3
• Molecular Formula: C12H17NO2
• Molecular Weight: 207.272
• Mol File: 43052-01-3.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: Oxaziridine, 2-(1,1-dimethylethyl)-3-(4-methoxyphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Oxaziridine, 2-(1,1-dimethylethyl)-3-(4-methoxyphenyl)-(43052-01-3)
• EPA Substance Registry System: Oxaziridine, 2-(1,1-dimethylethyl)-3-(4-methoxyphenyl)-(43052-01-3)

Safety Data

• Hazardous Substances Data: 43052-01-3(Hazardous Substances Data)

Upstream product

• 15875-74-8 N-(4-methoxybenzylidene)-2-methylpropan-2-amine 
• 123-11-5 4-methoxy-benzaldehyde 
• 75-64-9 tert-butylamine 
• 15875-74-8 (E)-tert-butyl[(4-methoxyphenyl)methylidene]amine 

Downstream Products

• 19486-73-8 N-tert-butyl-4-methoxybenzamide 
• 40117-28-0 N-(4-methoxy)benzylidene-t-butylamine N-oxide 
• 123-11-5 4-methoxy-benzaldehyde 
• 1193-82-4 racemic methyl phenyl sulfoxide 
• 15875-74-8 N-(4-methoxybenzylidene)-2-methylpropan-2-amine 
• 1253786-06-9 2-tert-butyl-3-(4-methoxyphenyl)-2,3-dihydrobenzo[d]isoxazole 
• 1253786-19-4 2-tert-butyl-3-(4-methoxyphenyl)-5,6-dimethyl-2,3-dihydrobenzo[d]isoxazole 
• 1253786-22-9 2-tert-butyl-1-(4-methoxyphenyl)-1,2-dihydronaphtho[1,2-d]isoxazole 

Relevant articles and documents

Weak base-promoted selective rearrangement of oxaziridines to amidesviavisible-light photoredox catalysis

The selective rearrangement of oxaziridines to amidesviaa single electron transfer (SET) pathway is unexplored. In this study, we present a weak base-promoted selective rearrangement of oxaziridines to amidesviavisible-light photoredox catalysis. The developed method shows excellent functional group tolerance with a broad substrate scope and good to excellent yields. Furthermore, control experiments and density functional theory (DFT) calculations are performed to gain insight into the reactivity and selectivity.

Synthesis of dihydrobenzisoxazoles by the [3 + 2] cycloaddition of arynes and oxaziridines

Dihydrobenzisoxazoles are readily prepared in good yields by the [3 + 2] cycloaddition of oxaziridines and arynes. The reaction involves an unusual cleavage of the C-O bond of the oxaziridine and tolerates a variety of substituents on the oxaziridine and the o-(trimethylsilyl)aryl triflate to form aryl-, heteroaryl-, alkyl-, and naphthyl-substituted dihydrobenzisoxazoles. The resulting halogen-substituted dihydrobenzisoxazoles are readily elaborated to more complex products using palladium-catalyzed crossing-coupling processes.

An environmentally friendly oxidation system for the selective oxygenation of aldimines to oxaziridines with anhydrous TBHP and alumina-supported MoO 3 as a recyclable heterogeneous catalyst

A highly efficient and selective protocol for the oxygenation of various aldimines to oxaziridines, which proceeds in excellent yields with enhanced selectivity by using alumina-supported M0O3 as a recyclable heterogeneous catalyst and anhydrous TBHP as the ultimate oxidant, is described. Wiley-VCH Verlag GmbH & Co. KGaA, 2007.