431-39-0Relevant articles and documents
METHOD FOR PRODUCING DIOL
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Paragraph 0083, (2018/12/04)
The present invention provides a method for producing a diol having a specific structure in high yields while keeping high selectivity. Provided is a method for producing a diol having a specific structure by oxidizing an olefin having a specific structure in the presence of a ruthenium compound.
Preparation method for coproduction of 3,3,3-trifluoro-1,2-propylene glycol and 4-trifluoromethyl ethylene carbonate
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Paragraph 0029-0030, (2018/05/30)
The invention discloses a preparation method for coproduction of 3,3,3-trifluoro-1,2-propylene glycol and 4-trifluoromethyl ethylene carbonate. The method includes the steps of: 1) in the presence ofa hydrogen halide solution and organic alkali, performing a reaction to 3,3,3-trifluoroepoxypropane and CO2 at 70-180 DEG C and under 0.1-5 MPa, after the reaction is finished, crude products of the 3,3,3-trifluoro-1,2-propylene glycol and 4-trifluoromethyl ethylene carbonate are produced; and 2) separating and purifying the crude products to obtain the target products, 3,3,3-trifluoro-1,2-propylene glycol and 4-trifluoromethyl ethylene carbonate, wherein the usage amount of the hydrogen halide is 0.5-20% of the molar weight of the 3,3,3-trifluoroepoxypropane and the usage amount of the organic alkali is 0.5-20% of the molar weight of the 3,3,3-trifluoroepoxypropane. The method has gentle reaction conditions and simple operations, is good in atom economy, and is adjustable in product distribution. The method is mainly used for coproduction of the 3,3,3-trifluoro-1,2-propylene glycol and the 4-trifluoromethyl ethylene carbonate.