431-66-3

Basic information

• Product Name: 2-Iodoperfluoroprop-1-ene 97%
• Synonyms: 2-Iodoperfluoroprop-1-ene 97%;2-Iodo-1,1,3,3,3-pentafluoroprop-1-ene;Perfluoro-2-iodoproprop-1-ene 97%;Perfluoro-2-iodoproprop-1-ene97%
• CAS NO: 431-66-3
• Molecular Formula: C₃F₅I
• Molecular Weight: 258
• Mol File: 431-66-3.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 44.9±35.0 °C(Predicted)
• Appearance: /
• Density: 2 +-.0.06 g/cm3(Predicted)
• CAS DataBase Reference: 2-Iodoperfluoroprop-1-ene 97%(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Iodoperfluoroprop-1-ene 97%(431-66-3)
• EPA Substance Registry System: 2-Iodoperfluoroprop-1-ene 97%(431-66-3)

Safety Data

• Hazardous Substances Data: 431-66-3(Hazardous Substances Data)

Upstream product

• 359-59-1 1-chloro-1,1,3,3,3-pentafluoro-2-iodo-propane 
• 1375484-87-9 N(C₄H₉)4⁽¹⁺⁾*CF₂C(CF₃)BF₃^(1-)=N(C₄H₉)4[CF₂C(CF₃)BF₃] 
• 137005-93-7 C₃F₅IZn 
• 38568-21-7 2,2-dibromo-1,1,1,3,3,3-hexafluoropropane 

Downstream Products

• 146500-63-2 1-bromo-4-(perfluoroprop-1-en-2-yl)benzene 
• 146500-61-0 3-nitro-β,β-difluoro-α-(trifluoromethyl)styrene 

Relevant articles and documents

Reactions of perfluorinated alkenyl-, alkynyl-, alkyltrifluoroborates, and selected hydrocarbon analogues with the halogenating agents Hal2 (Hal = F, Cl, Br), "brF" (BrF3-Br2 1:1), and ICl

Reactions of [Bu4N][RBF3] [R = CnF 2n+1CF=CF (cis, trans), CF2=CF, CF2=C(CF 3), trans-C4H9CF=CF, trans-C6H 5CF=CF, C4H9CH=CH (cis, trans), CF 3C≡C, and C4H9C≡C] with chlorine, bromine, BrF3 + Br2 (as equivalent of "BrF"), and ICl in solution (CH2Cl2, CHCl3, CF 3CH2CF2CH3) led to 1, 2-addition of halogen and/or replacement of boron by halogen (halodeboration). The reaction of [Bu4N][CF3C≡CBF3] with less than equimolar amounts of diluted fluorine (5 %) in 1, 1, 1, 3, 3-pentafluorobutane (PFB) showed only [Bu4N][CF3CF2CF 2BF3] as fluorine addition product besides extensive fluorodeboration. Suspensions of the insoluble K[CF2=CFBF 3] salt reacted with Cl2 and Br2 in CH 2Cl2 giving preferentially products of halogen addition across the C=C bond. In reactions with ICl iododeboration with formation of CF2=CFI occurred besides 1, 2-addition with formation of [CF 2I-CFClBF3]-. The halodeboration reaction of[Bu4N][trans-C4H9CF=CFBF3] with Br2, "BrF", and ICl, of K[trans-C6H 5CF=CFBF3] with Br2, and of [Bu 4N][trans-C4F9CF=CFBF3] with ICl proceeded stereospecifically. Copyright

Convenient Preparation and Functionalization of 2-Metallated Pentafluoropropenes

The title compounds are prepared by metallation of CF3CH=CF2 with LDA or t-BuLi or by metallation of CF3CBr2CF3 with 2 equivalents of zinc.CF3C(ZnX)=CF2 undergoes halogenation, oxidative dimerization, allylation and acylation reactions. Key Words: vinyl organofluorine zinc reagent; organolithium; zinc; oxidative coupling; halogenation