466-09-1Relevant articles and documents
CARDENOLIDE DIGLYCOSIDES FROM OXYSTELMA ESCULENTUM
Srivastava, Suman,Khare, Maheshwari P.,Khare, Anakshi
, p. 1019 - 1022 (2007/10/02)
Two new cardenolide diglycosides, named oxystelmoside and oxystelmine, were isolated from the dried roots of Oxystelma esculentum.On the basis of chemical and spectroscopic evidence their structures were established as uzarigenin 3-O-β-D-xylopyranosyl(1->4)-O-β-D-digitalopyranoside and periplogenin 3-O-6-deoxy-β-D-glucopyranosyl(1->4)-α-D-digitalopyranoside. Key Word Index - Oxystelma esculentum; Asclepiadaceae; roots; oxystelmoside; oxystelmine; steroid; cardenolide glycoside.
BIOTRANSFORMATION OF DIGITOXIGENIN BY GINSENG HAIRY ROOT CULTURES
Kawaguchi, Kiichiro,Hirotani, Masao,Yoshikawa, Takafumi,Furuya, Tsutomu
, p. 837 - 843 (2007/10/02)
Five new compounds (three esters and two glycosides) and seven previously reported compounds were isolated as biotransformation products of digitoxigenin by ginseng hairy root cultures.The new esters and glycosides were elucidated as digitoxigenin stearate, digitoxigenin palmitate, digitoxigenin myristate, 3-epidigitoxigenin β-D-gentiobioside and digitoxigenin β-D-sophoroside using 1H and 13C NMR and FAB mass spectral data.Biotransformations involving esterification (of stearic acid, palmitic acid, myristic acid and lauric acid) and glycosylation (of gentiobiose and sophorose) of digitoxigenin have been demonstrated for the first time in the plant cell and tissue cultures.The hairy roots showed high glycosylation ability to the digitoxigenin molecule.
Studies on Cerbera. V. Minor glycosides of 17α-digitoxigenin from the stems of genus Cerbera
Yamauchi,Abe,Wan
, p. 4993 - 4995,4993-4995 (2007/10/02)
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