4728-14-7Relevant articles and documents
Development of new methods for the synthesis of 2,3-bis(nitroxymethyl)-2,3-dinitrobutane-1,4-diol dinitrate and its intermediates
Khisamutdinov, G. Kh.,Karpychev, Yu. V.,Zhbanova, Yu. S.,Kondyukov,Kashaev,Il′in
, p. 1967 - 1970 (2015)
Known methods for the synthesis of 2,3-bis(nitroxymethyl)-2,3-dinitrobutane-1,4-diol dinitrate and its intermediates were investigated. New procedures were developed for the preparation of these compounds. 2,3-Bis(nitroxymethyl)-2,3-dinitrobutane-1,4-diol dinitrate was studied by X-ray diffraction.
Polynitrocarbamates Derived from Nitromethane
Klap?tke, Thomas M.,Krumm, Burkhard,Reith, Thomas
, p. 1474 - 1481 (2017/09/13)
A variety of energetic compounds combining nitro with nitrocarbamate groups were synthesized. The precursors, polynitro alcohols, were obtained by the condensation of the readily available starting material nitromethane with the small aliphatic aldehydes formaldehyde and glyoxal. The conversion into carbamates was achieved with the reactive chlorosulfonyl isocyanate (CSI) and a final nitration yielded the polynitrocarbamates. The new compounds were fully characterized, including multinuclear NMR spectroscopy, vibrational analysis, mass spectrometry, differential scanning calorimetry, and elemental analysis. The energies of formation were calculated with the GAUSSIAN program package and the detonation parameters were predicted using the EXPLO5 computer code. Due to the positive oxygen balance (ΩCO) of the presented compounds, their performance data as oxidizers were determined and compared to the common oxidizer ammonium perchlorate.
Synthesis and crystal structure of 5,5'-dinitro-[5,5'-bi-(1,3,2- dioxathiane)]2,2'-dioxide
Zhang, Pan,Li, Jia-Rong,Yang, De-Li,Shi, Da-Xin
, p. 464 - 466 (2014/11/08)
A novel 1,3,2-dioxathiane-2-oxide derivative 5,5'-dinitro-[5,5'-bis(1,3,2- dioxathiane)]2,2'-dioxide was synthesised. Moreover, the molecular structure of the compound was confirmed by the X-ray crystal structure determination.