4746-32-1

Basic information

• Product Name: N-HEXYLANILINE, 98%
• Synonyms: N-n-Hexylaniline, 98%
• CAS NO: 4746-32-1
• Molecular Formula: C₁₂H₁₉N
• Molecular Weight: 177.29
• Product Categories: Amines;C11 to C38;Nitrogen Compounds
• Mol File: 4746-32-1.mol
• Article Data: 141

Chemical Properties

• Boiling Point: 140-145 °C/15 mmHg
• Flash Point: 110 °C
• Appearance: Colorless to brown/Liquid
• Density: 0.8994 g/mL at 25 °C
• Vapor Pressure: 0.0049mmHg at 25°C
• Refractive Index: n20/D 1.5228
• PKA: 5.05±0.50(Predicted)
• CAS DataBase Reference: N-HEXYLANILINE, 98%(CAS DataBase Reference)
• NIST Chemistry Reference: N-HEXYLANILINE, 98%(4746-32-1)
• EPA Substance Registry System: N-HEXYLANILINE, 98%(4746-32-1)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26
• WGK Germany: 3
• Hazardous Substances Data: 4746-32-1(Hazardous Substances Data)

Usage

Description

N-HEXYLANILINE, 98% is a chemical compound with a purity of 98%, belonging to the class of aniline organic compounds derived from benzene. It is specifically composed of a hexyl group attached to the amine functional group, known for its strong odor and versatile industrial applications.

Uses

Used in Chemical Production:
N-HEXYLANILINE, 98% is used as an intermediate in the production of dyes, pigments, and other organic compounds, contributing to the coloration and enhancement of various products.
Used in Textile Industry:
In the textile industry, N-HEXYLANILINE, 98% is utilized for dyeing and finishing processes, providing color and improving the quality of fabrics.
Used in Plastics and Rubber Manufacturing:
This chemical compound is employed in the manufacturing of plastics and rubber, where it serves to modify properties such as flexibility, durability, and color.
Used as a Catalyst in Chemical Reactions:
N-HEXYLANILINE, 98% is used as a catalyst to facilitate various chemical reactions, enhancing the efficiency and speed of these processes.
Used in Metalworking Processes:
As a corrosion inhibitor, N-HEXYLANILINE, 98% is applied in metalworking processes to protect metals from corrosion, ensuring the longevity and integrity of metal components.

InChI:InChI=1/C12H19N/c1-2-3-4-8-11-13-12-9-6-5-7-10-12/h5-7,9-10,13H,2-4,8,11H2,1H3

Upstream product

• 638-45-9 1-Iodohexane 
• 62-53-3 aniline 
• 111-25-1 1-bromo-hexane 
• 103-70-8 Formanilid 
• 66-25-1 hexanal 
• 98-95-3 nitrobenzene 
• 111-26-2 hexan-1-amine 
• 108-90-7 chlorobenzene 
• 108-86-1 bromobenzene 
• 21369-64-2 n-hexyllithium 
• 52144-59-9 (Z)-(tert-butylsulfanyl)(phenyl)diazene 
• 591-50-4 iodobenzene 
• 67-63-0 isopropyl alcohol 
• 17763-67-6 Phenyl triflate 

Downstream Products

• 37877-50-2 N-hexyl-toluene-4-sulfonanilide 
• 50917-04-9 chloro-acetic acid-(N-hexyl-anilide) 
• 33228-45-4 4-hexylaniline 
• 62-53-3 aniline 
• 66-25-1 hexanal 
• 1263079-29-3 C₄₅H₆₃N₃ 
• 1202804-81-6 C₃₂H₄₄N₂ 
• 1202804-72-5 C₃₂H₄₄N₂ 
• 72450-68-1 N-benzyl-N-hexyl aniline 
• 1202804-71-4 C₃₂H₄₄N₂ 
• 1581704-09-7 C₁₇H₁₈N₄ 
• 52790-65-5 N-(2,4-dinitrophenyl)hexylamine 

Relevant articles and documents

Mechanistic Analysis of Metallaphotoredox C-N Coupling: Photocatalysis Initiates and Perpetuates Ni(I)/Ni(III) Coupling Activity

The combined use of reaction kinetic analysis, ultrafast spectroscopy, and stoichiometric organometallic studies has enabled the elucidation of the mechanistic underpinnings to a photocatalytic C-N cross-coupling reaction. Steady-state and ultrafast spect

Solvent-dependent nuclearity, geometry and catalytic activity of [(SPhos)Pd(Ph)Cl]2

The nuclearity and structures of the palladium complex [(SPhos)Pd(Ph)Cl]2 in the solid and solution states are revisited using a combination of Extended X-ray Absorption Fine Structure (EXAFS) spectroscopy, NMR spectroscopy, mass spectrometry,

Reductive amination of ketones/aldehydes with amines using BH3N(C2H5)3as a reductant

Herein, we report the first example of efficient reductive amination of ketones/aldehydes with amines using BH3N(C2H5)3 as a catalyst and a reductant under mild conditions, affording various tertiary and secondary amines in excellent yields. A mechanistic study indicates that BH3N(C2H5)3 plays a dual function role of promoting imine and iminium formation and serving as a reductant in reductive amination. This journal is

Ruthenium(ii) complexes with N-heterocyclic carbene-phosphine ligands for theN-alkylation of amines with alcohols

Metal hydride complexes are key intermediates forN-alkylation of amines with alcohols by the borrowing hydrogen/hydrogen autotransfer (BH/HA) strategy. Reactivity tuning of metal hydride complexes could adjust the dehydrogenation of alcohols and the hydrogenation of imines. Herein we report ruthenium(ii) complexes with hetero-bidentate N-heterocyclic carbene (NHC)-phosphine ligands, which realize smart pathway selection in theN-alkylated reactionviareactivity tuning of [Ru-H] species by hetero-bidentate ligands. In particular, complex6cbwith a phenyl wingtip group and BArF?counter anion, is shown to be one of the most efficient pre-catalysts for this transformation (temperature is as low as 70 °C, neat conditions and catalyst loading is as low as 0.25 mol%). A large variety of (hetero)aromatic amines and primary alcohols were efficiently converted into mono-N-alkylated amines in good to excellent isolated yields. Notably, aliphatic amines, challenging methanol and diamines could also be transformed into the desired products. Detailed control experiments and density functional theory (DFT) calculations provide insights to understand the mechanism and the smart pathway selectionvia[Ru-H] species in this process.