4762-79-2Relevant articles and documents
PalladIum-catalyzed enantioselective allylic phosphination
Butti, Pietro,Rochat, Raphael,Sadow, Aaron D.,Togni, Antonio
experimental part, p. 4878 - 4881 (2009/02/08)
(Chemical Equation Presented) A new cat. for chiral phosphines: A highly enantioselective allylic phosphination reaction is realized using the Pd-Josiphos(L) catalyst system. This C-P bond forming reaction provides a new access to chiral phosphines (see scheme) that may be further functionalized. Cy=cyclohexyl, dba=trans,trans-dibenzylideneacetone.