479423-39-7

Basic information

• Product Name: Carbamic acid, [(4-methylphenyl)methylene]-, 1,1-dimethylethyl ester (9CI)
• Synonyms: Carbamic acid, [(4-methylphenyl)methylene]-, 1,1-dimethylethyl ester (9CI);(4-Methyl-BENZYLIDENE)-CARBAMIC ACID TERT-BUTYL ESTER;(E)-tert-Butyl 4-MethylbenzylidenecarbaMate
• CAS NO: 479423-39-7
• Molecular Formula: C₁₃H₁₇NO₂
• Molecular Weight: 219.27958
• Product Categories: N-BOC
• Mol File: 479423-39-7.mol
• Article Data: 25

Chemical Properties

• Appearance: /
• Storage Temp.: 2-8°C
• CAS DataBase Reference: Carbamic acid, [(4-methylphenyl)methylene]-, 1,1-dimethylethyl ester (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamic acid, [(4-methylphenyl)methylene]-, 1,1-dimethylethyl ester (9CI)(479423-39-7)
• EPA Substance Registry System: Carbamic acid, [(4-methylphenyl)methylene]-, 1,1-dimethylethyl ester (9CI)(479423-39-7)

Safety Data

• Hazardous Substances Data: 479423-39-7(Hazardous Substances Data)

Usage

General Description

Carbamic acid, [(4-methylphenyl)methylene]-, 1,1-dimethylethyl ester (9CI) is a chemical compound that belongs to the class of carbamic acid derivatives. It is also known as tert-butyl N-(p-tolyl)carbamate and has the molecular formula C13H17NO2. Carbamic acid, [(4-methylphenyl)methylene]-, 1,1-dimethylethyl ester (9CI) is commonly used in organic synthesis and pharmaceutical research as a reagent and intermediate. It is a colorless liquid with a high boiling point, making it suitable for various chemical reactions. Additionally, this compound may have potential applications in the agricultural and pharmaceutical industries due to its structural properties and reactivity. However, it is important to handle and use this chemical with caution due to its potential hazards and toxicity.

Upstream product

• 365441-83-4 tert-butyl (p-tolyl(tosyl)methyl)carbamate 
• 479423-27-3 tert-butyl (phenylsulfonyl(p-tolyl)methyl)carbamate 
• 4248-19-5 tert-butyl carbazate 
• 104-87-0 4-methyl-benzaldehyde 
• 24424-99-5 di-tert-butyl dicarbonate 

Downstream Products

• 442521-15-5 {5-(4-bromo-phenyl)-4-[dimethyl-(1,1,2-trimethyl-propyl)-silanyl]-2-methyl-3-oxo-1-p-tolyl-pentyl}-carbamic acid tert-butyl ester 
• 875304-24-8 tert-butyl (1R,2S)-1-(p-methylphenyl)-2-nitro-3-phenylpropylcarbamate 
• 1039201-63-2 tert-butyl (1R,2S)-2-nitro-1-p-tolylpropylcarbamate 
• 1073903-10-2 (2R,3S)-1-(t-butoxycarbonyl)-N-phenyl-3-(4-tolyl)aziridine-2-carboxamide 
• 1043872-95-2 C₃₃H₃₈N₂O₅ 
• 1070443-92-3 (2S,3R)-tert-butyl 3-(tert-butoxycarbonylamino)-2-nitro-3-p-tolylpropanoate 

Relevant articles and documents

Enantioselective Construction of Sulfur-Containing Tetrasubstituted Stereocenters via Asymmetric Functionalizations of α-Sulfanyl Cyclic Ketones

Asymmetric functionalizations of α-sulfanyl cyclic ketones were realized via chiral phosphoric acid catalyzed enantioselective addition reactions with aldimines, azodicarboxylates and allenamides. A series of chiral organosulfur compounds possessing sulfur-containing tetrasubstituted stereocenters were accessed via these methods, with excellent regioselectivities and high stereoselectivities. (Figure presented.).

γ-Selective Vinylogous Aza-Morita-Baylis-Hillman Reaction with N -Carbamoylimines

Vinylogous aza-Morita-Baylis-Hillman (aza-MBH) reactions of a vinylcyclopentenone with N -Boc imines provide the corresponding γ-adducts in high regioselectivity (10 examples). While the corresponding reactions with N -Ts imines give the α-adducts and γ-a

Direct enantioselective Mannich reactions of α-azido cyclic ketones: Asymmetric construction of chiral azides possessing an α-quaternary stereocenter

Direct enantioselective Mannich reactions of α-azido cyclic ketones with aldimines are realized through chiral phosphoric acid catalysis, which generate chiral azides possessing an α-quanternary stereocenter with complete regioselectivities and high diast