49603-23-8

Basic information

• Product Name: Benzenemethanamine, N-methyl-a-2-propenyl-
• CAS NO: 49603-23-8
• Molecular Formula: C11H15N
• Molecular Weight: 161.247
• Mol File: 49603-23-8.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: Benzenemethanamine, N-methyl-a-2-propenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanamine, N-methyl-a-2-propenyl-(49603-23-8)
• EPA Substance Registry System: Benzenemethanamine, N-methyl-a-2-propenyl-(49603-23-8)

Safety Data

• Hazardous Substances Data: 49603-23-8(Hazardous Substances Data)

Upstream product

• 622-29-7 N-Benzylidenemethylamine 
• 106-95-6 allyl bromide 
• 24850-33-7 allyltributylstanane 
• 18854-66-5 tris(allyl)aluminum 
• 25521-74-8 N-benzylidenemethylamine 
• 100-52-7 benzaldehyde 
• 74-89-5 methylamine 
• 103-67-3 benzyl-methyl-amine 
• 3555-71-3 N-benzyl-N-chloromethylamine 
• 1730-25-2 allylmagnesium bromide 
• 3376-23-6 N-methyl-α-phenylnitrone 
• 3376-23-6 C-phenyl-N-methylnitrone 
• 762-72-1 allyl-trimethyl-silane 
• 101246-18-8 2-Methyl-3-phenyl-5-trimethylsilanylmethyl-isoxazolidine 

Relevant articles and documents

Metallic bismuth and tantalum mediated C-allylation of aldimines with allyl bromide

A facile method for the synthesis of homoallyl amines using Bi/BU4NBr/MeCN and Ta/Bu4NBr/ THF system has been performed in a regiospecific manner.

Preparation of 2-azaallyl anions and imines from N-chloroamines and their cycloaddition and allylation

Exposure of N-chloroamines to KOtBu or LDA, in the presence of PMDETA or HMPA, provides 2-azaallyl anions capable of π4s + π2s cycloaddition reactions with a range of olefins. Good yields were achieved with stabilised systems, however, they were more modest when accessing semi-stabilised 2-azaallyl anions. By modifying the reaction conditions, one-pot dehydrochlorination/allylation can also be achieved with a range of N-chloroamines.

Allylic Tantalums as Highly Imine-Selective Reagents

A pratical method for the allylation of low electrophilic N-aliphatic imines was established by allylic tantalum. This is a superior methodology compared with conventional ones in terms of wide applicability to imines.