49774-14-3Relevant articles and documents
Selective Reductions of N,N-Bis{chloro(aryl)-phosphino}-amines Yielding Three-, Five-, Six-, and Eight-Membered Cyclic Azaphosphanes
H?hne, Martha,Joksch, Markus,Konieczny, Katharina,Müller, Bernd H.,Spannenberg, Anke,Peulecke, Normen,Rosenthal, Uwe
, p. 4298 - 4309 (2017)
To date, a plethora of λ3-P nitrogen-containing compounds is known. A large number of them are used as ligands in coordination chemistry and homogeneous catalysis. PN-containing compounds tend to build up cyclic moieties, which have received less attention in regard to their application as ligands in transition metal chemistry. Hence, different dehalogenation reactions of N,N-bis{chloro(aryl)-phosphino}-amines have been developed to synthesize different P-N-P containing cyclic compounds. Their coordination behavior to group VI transition metal carbonyls was explored.
