50298-32-3

Basic information

• Product Name: trans-Pt(SCF₃)2(PPh₃)2
• CAS NO: 50298-32-3
• Molecular Weight: 921.806
• Mol File: 50298-32-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: trans-Pt(SCF₃)2(PPh₃)2(CAS DataBase Reference)
• NIST Chemistry Reference: trans-Pt(SCF₃)2(PPh₃)2(50298-32-3)
• EPA Substance Registry System: trans-Pt(SCF₃)2(PPh₃)2(50298-32-3)

Safety Data

• Hazardous Substances Data: 50298-32-3(Hazardous Substances Data)

Upstream product

• 14221-02-4 tetrakis(triphenylphosphine)platinum 
• 372-64-5 Bis(trifluoromethyl)disulfid 
• 10199-34-5 cis-dichlorobis(triphenylphosphine)platinum(II) 
• 811-68-7 silver(I) trifluoromethanethiolate 
• 21264-32-4 diacetonitriledichloridopalladium(II) 
• 603-35-0 triphenylphosphine 

Relevant articles and documents

Syntheses of trifluoromethanethiolato platinum(II) complexes - Crystal structures of cis-Pt(SCF3)2(PPh3)2 and trans-Pt(SCF3)Cl(PPh3)2

Ligand exchange reactions of cis-PtCl2(PPh3) 2 and [NMe4]SCF3 in different ratios were studied. Depending on the stoichiometry reactions proceeded with formation of products expected for the chosen ratio, i. e. cis-Pt(SCF3)Cl(PPh 3)2, cis-Pt(SCF3)2(PPh 3)2, and [NMe4][Pt(SCF3) 3(PPh3)]. Starting from cis-PtCl2(MeCN) 2 and [NMe4]SCF3 and adding PPh3 after substitution, product mixtures were dominated by the corresponding trans-isomers. Results of the single crystal structure analyses of cis-Pt(SCF3)2(PPh3)2 and trans-Pt(SCF3)Cl(PPh3)2 are discussed.