50389-70-3

Basic information

• Product Name: 1-Bromo-2-ethoxynaphthalene
• Synonyms: 1-Bromo-2-ethoxynaphthalene
• CAS NO: 50389-70-3
• Molecular Formula: C₁₂H₁₁BrO
• Molecular Weight: 251.11914
• Mol File: 50389-70-3.mol
• Article Data: 7

Chemical Properties

• Appearance: /
• Storage Temp.: 2-8°C
• CAS DataBase Reference: 1-Bromo-2-ethoxynaphthalene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Bromo-2-ethoxynaphthalene(50389-70-3)
• EPA Substance Registry System: 1-Bromo-2-ethoxynaphthalene(50389-70-3)

Safety Data

• Hazardous Substances Data: 50389-70-3(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Synthetic Communications, 25, p. 2401, 1995 DOI: 10.1080/00397919508015443

Upstream product

• 7072-23-3 1,3-dibromo-5,5-dimethyl-hydantoin 
• 93-18-5 2-ethoxynaphthalene 
• 77-48-5 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione 
• 7726-95-6 bromine 
• 64-19-7 acetic acid 
• 573-97-7 1-bromo-2-naphthol 
• 75-03-6 ethyl iodide 
• 74-96-4 ethyl bromide 
• 135-19-3 β-naphthol 

Downstream Products

• 573-97-7 1-bromo-2-naphthol 
• 148345-64-6 (2-ethoxynaphthalen-1-yl)boronic acid 
• 36233-70-2 Mesityl-α-(β-ethoxy-naphthyl)-methan 
• 36342-55-9 Mesityl-α(β-ethoxynaphthyl)carbinol 
• 118-30-9 2-ethoxynaphthalen-1-amine 

Relevant articles and documents

PLATIN-KOHLENSTOFF-?-BINDUNGEN MIT GEHINDERTER ROTATION: 4-BICYCLOHEPTA-2,5-DIEN>-(E)-BIS(2-ETHOXYNAPHTH-1-YL)PLATIN(II)

The synthesis of 4-bicyclohepta-2,5-diene>-(E)-bis(2-ethoxy-naphth-1-yl)platinum(II) has been described.As a consequence of the two adjacent naphthalene rings the compound has a stationary E-conformation; there is no rotation about the platinum-carbon ?-bonds.

Aerobic oxidative bromination of arenes using an ionic liquid as both the catalyst and the solvent

A method for the bromination of alkoxy-substituted benzenes and naphthalenes was developed by using the residual oxygen in the reaction tube as the oxidant, and [Bmim]NO3 (1-butyl-3-methylimidazolium nitrate) ionic liquid as both the catalyst and the solvent. No other reagent apart from the ionic liquid and molecular bromine was used in the reactions, and basically all the bromine atoms in the bromine source were transferred to the bromination products, showing that the presented protocol is highly atom economic and practical.

Highly selective insertion of arynes into a C(sp)-O(sp3) σ Bond

Arynes react with ethoxyacetylene to afford 2-ethoxyethynylaryl derivatives through a highly chemo-and regioselective formal insertion of the aryne into the C(sp)-O(sp3) bond of the alkyne. Computational studies suggest that the reaction does n