51241-40-8

Basic information

• Product Name: Benzene, 1-chloro-4-(pentyloxy)-
• Synonyms: 4-chlorophenyl penthyl ether;4-Chlor-1-pentyloxy-benzol
• CAS NO: 51241-40-8
• Molecular Formula: C11H15ClO
• Molecular Weight: 198.692
• Mol File: 51241-40-8.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: Benzene, 1-chloro-4-(pentyloxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-chloro-4-(pentyloxy)-(51241-40-8)
• EPA Substance Registry System: Benzene, 1-chloro-4-(pentyloxy)-(51241-40-8)

Safety Data

• Hazardous Substances Data: 51241-40-8(Hazardous Substances Data)

Upstream product

• 110-53-2 1-Bromopentane 
• 106-48-9 4-chloro-phenol 
• 2050-04-6 (pentyloxy)benzene 
• 75-24-1 trimethylaluminum 
• 1043963-12-7 4-(4-bromopentyloxy)chlorobenzene 
• 1225507-55-0 C₁₁H₁₅ClO₂ 
• 106-46-7 para-dichlorobenzene 
• 71-41-0 pentan-1-ol 
• 106-39-8 bromochlorobenzene 

Relevant articles and documents

Cobalt-Catalyzed Decarboxylative Methylation and Ethylation of Aliphatic N-(Acyloxy)phthalimides with Organoaluminum Reagents

A cobalt-catalyzed decarboxylative methylation of aliphatic redox-active esters [ N-(acyloxy)phthalimides; RAEs] with trimethylaluminum under mild conditions was developed, providing a method for transforming a carboxylate group into a methyl group without redox fluctuation. Primary and secondary RAEs were both amenable substrates, whereas a tertiary RAE delivered an elimination product. Triethylaluminum was also used to deliver a decarboxylative ethylation product.

Copper-catalyzed reduction of alkyl triflates and iodides: An efficient method for the deoxygenation of primary and secondary alcohols

We describe an effective method for catalytic reduction of 1°alkyl sulfonates, and 1°and 2°iodides in the presence of a wide range of functional groups. This Cu-catalyzed reaction provides a means for the effective deoxygenation of alcohols, as demonstrated by the highly selective reduction of 1°alcohols using a triflation/reduction sequence. A preliminary study of the reaction mechanism suggests that the reduction does not involve free-radical intermediates. Primarily reduced: The copper-catalyzed reduction of 1°alkyl sulfonates, and 1°and 2°iodides, which is effective in the presence of a wide range of functional groups, provides a means for the effective deoxygenation of alcohols. A preliminary study of the reaction mechanism suggests that the reduction does not involve free-radical intermediates. Copyright

Regiospecific aromatic chlorination of alkyl phenyl ethers using sodium chlorite catalysed by manganese(III) acetylacetonate and moist alumina in dichloromethane

A solid-liquid biphasic system (dichloromethane and chromatographic neutral alumina) has been tested for the aromatic chlorination of various alkyl aryl ethers using a reagent combination of sodium chlorite and manganese(III) acetylacetonate catalyst. Efficient incorporation of a chlorine atom into the benzene ring with high para-selectivity results. This catalytic system is also applicable to the regiocontrolled chlorination of polyether substrates.