516493-75-7

Basic information

• Product Name: benzyl 4-[1-(1,3-dithian-2-yl)-cyclohexyl]-but-2-enoate
• Synonyms: benzyl 4-[1-(1,3-dithian-2-yl)-cyclohexyl]-but-2-enoate
• CAS NO: 516493-75-7
• Molecular Weight: 362.557
• Mol File: 516493-75-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: benzyl 4-[1-(1,3-dithian-2-yl)-cyclohexyl]-but-2-enoate(CAS DataBase Reference)
• NIST Chemistry Reference: benzyl 4-[1-(1,3-dithian-2-yl)-cyclohexyl]-but-2-enoate(516493-75-7)
• EPA Substance Registry System: benzyl 4-[1-(1,3-dithian-2-yl)-cyclohexyl]-but-2-enoate(516493-75-7)

Safety Data

• Hazardous Substances Data: 516493-75-7(Hazardous Substances Data)

Upstream product

• 57443-18-2 benzyl 2-(dimethoxyphosphoryl)acetate 
• 516493-73-5 1-(1,3-dithian-2-yl)cyclohexanecarboxaldehyde 
• 7396-44-3 benzyl diethylphosphonoacetate 

Downstream Products

• 516493-78-0 benzyl 3-(1-formyl-cyclohexyl)-prop-2-enoate 

Relevant articles and documents

SmI2-mediated 3-exo-trig cyclisation of δ-oxo-α, β-unsaturated esters to cyclopropanols and derivatives

In the presence of samarium diiodide and a proton source, δ-oxo-γ,γ-disubstituted-α,β-unsaturated esters of general formula R-CO-C(R′,R′)-CHCH-CO2Bn readily cyclise to trans-cyclopropanol products and/or lactones derived from the cis isomers. F