52755-39-2

Basic information

• Product Name: Benzenemethanol, a-(1E)-1-propenyl-
• CAS NO: 52755-39-2
• Molecular Formula: C10H12O
• Molecular Weight: 148.205
• Mol File: 52755-39-2.mol
• Article Data: 56

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, a-(1E)-1-propenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, a-(1E)-1-propenyl-(52755-39-2)
• EPA Substance Registry System: Benzenemethanol, a-(1E)-1-propenyl-(52755-39-2)

Safety Data

• Hazardous Substances Data: 52755-39-2(Hazardous Substances Data)

Upstream product

• 590-15-8 trans-2-propenyl bromide 
• 100-52-7 benzaldehyde 
• 6249-80-5 1-phenylbut-3-en-1-one 
• 98-88-4 benzoyl chloride 
• 6386-72-7 (E)-propenyl lithium 
• 123-73-9 trans-Crotonaldehyde 
• 108-86-1 bromobenzene 
• 100-59-4 phenylmagnesium chloride 
• 123-73-9 crotonaldehyde 
• 591-50-4 iodobenzene 
• 80735-94-0 1-Phenyl-3-buten-1-ol 
• 13154-14-8 1-propenylmagnesium bromide 
• 100-58-3 phenylmagnesium bromide 
• 1730-25-2 (E)-1-propenylmagnesium bromide 

Downstream Products

• 82045-04-3 (rac)-(E)-2-acetoxy-4-phenylbut-3-ene 
• 17180-62-0 (3-methyloxiran-2-yl)(phenyl)methanone 
• 35660-91-4 (Z)-1-phenylbut-2-en-1-one 
• 495-41-0 1-phenylbut-2-en-1-one 
• 74608-23-4 4-methyl-N-[(2E)-1-methyl-3-phenyl-2-propen-1-yl]benzenesulfonamide 
• 1123669-90-8 C₁₂H₁₄OS 
• 35660-91-4 (E)-1-phenyl-2-buten-1-one 
• 51765-78-7 2-methyl-4-oxo-4-phenylbutanenitrile 
• 938-87-4 2-methyl-1-phenyl-butan-1-one 
• 42461-65-4 (E)-(pent-3-en-2-yl)benzene 
• 15325-56-1 (Z)-3-methyl-1-phenylbut-1-ene 
• 15325-61-8 (E)-(3-methylbut-1-en-1-yl)benzene 
• 76807-04-0 (Z)-(pent-3-en-2-yl)benzene 
• 51801-01-5 (E)-1-acetoxy-1-phenyl-2-butene 

Relevant articles and documents

New γ-Halo-δ-lactones and δ-Hydroxy-γ-lactones with Strong Cytotoxic Activity

This paper presents the synthesis of γ-halo-δ-lactones, δ-iodo-γ-lactones and δ-hydroxy-γ-lactones from readily available organic substrates such as trans-crotonaldehyde and aryl bromides. Crystal structure analysis was carried out for lactones that were obtained in crystalline form. All halo-δ-lactones and δ-hydroxy-γ-lactones were highly cytotoxic against gastric cancer AGS cells with IC50 values in the range of 0.0006–0.0044 mM. Some lactones showed high bactericidal activity against E. coli ATCC 8739 and S. aureus ATCC 65389, which reduced the number of CFU/mL by 70–83% and 87% respectively.

Modular access to 1,2-allenyl ketones based on a photoredox-catalysed radical-polar crossover process

Herein, a new protocol dealing with the preparation of 1,2-allenyl ketones has been successfully developedviathe reactions of enynes with radicals enabled by dual photoredox/copper catalysis. Based on the results of a deuteration experiment and the competition reaction between cyclopropanation and allenation, the mechanism based on a photoredox-neutral-catalysed radical-polar crossover process has been proposed. Synthetic applications of allenes have also been demonstrated.

A Pd-Catalyzed Site-Controlled Isomerization of Terminal Olefins

An effective Pd-catalyzed isomerization of olefins with 2-PyPPh2 as the ligand is described. A wide variety of trans-2-olefins bearing various functional groups can be obtained with high regio- A nd stereoselectivity under mild reaction conditions. The ligand is crucial for the reaction.