52776-36-0Relevant articles and documents
Photolysis of (3-methyl-2H-azirin-2-yl)-phenylmethanone: Direct detection of a triplet vinylnitrene intermediate
Rajam, Sridhar,Murthy, Rajesh S.,Jadhav, Abhijit V.,Li, Qian,Keller, Christopher,Carra, Claudio,Pace, Tamara C.S.,Bohne, Cornelia,Ault, Bruce S.,Gudmundsdottir, Anna D.
supporting information; experimental part, p. 9934 - 9945 (2012/02/03)
The photoreactivity of (3-methyl-2H-azirin-2-yl)-phenylmethanone, 1, is wavelength-dependent (Singh et al. J. Am. Chem. Soc. 1972, 94, 1199-1206). Irradiation at short wavelengths yields 2P, whereas longer wavelengths produce 3P. Laser flash photolysis of
Regioselective synthesis of (trifluoromethyl)-β-chloroenones
Alvernhe, Gerard,Bensadat, Abdelkader,Ghobsi, Abdelkader,Laurent, Andre,Laurent, Eliane
, p. 169 - 172 (2007/10/03)
The regioselectivity of the conversion of 1,3-diketones into β-chloroenones can be changed by the appropriate choice of the reagent: reaction with "Vilsmeier's reagent" prepared from POCl3 and dimethylformamide or treatment of the diketone with the oxalyl chloride in the presence of dimethylformamide.
Hydrochloration des cetones alleniques. Synthese stereoselective de β-chlorenones conjuguees E
Gras, Jean-Louis,Galledou, Bocar Sally
, p. 89 - 95 (2007/10/02)
β-Chlorenones are valuable intermediates in organic synthesis.We report on a new stereoselective synthesis of these compounds under mild experimental conditions.Hydrohalogenation of allenes is an electrophilic process leading to various results, depending
