53044-24-9

Basic information

• Product Name: 2-(Phenylamino)benzenemethanol
• Synonyms: 2-(Phenylamino)benzenemethanol
• CAS NO: 53044-24-9
• Molecular Formula: C₁₃H₁₃NO
• Molecular Weight: 199.25
• Mol File: 53044-24-9.mol
• Article Data: 6

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-(Phenylamino)benzenemethanol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(Phenylamino)benzenemethanol(53044-24-9)
• EPA Substance Registry System: 2-(Phenylamino)benzenemethanol(53044-24-9)

Safety Data

• Hazardous Substances Data: 53044-24-9(Hazardous Substances Data)

Upstream product

• 91-40-7 2-(phenylamino)benzoic acid 
• 23868-11-3 ethyl 2-(phenylamino)benzoate 
• 20877-86-5 N-phenyl isatoic anhydride 
• 87199-14-2 2-(hydroxymethyl)phenylboronic acid 
• 586-96-9 Nitrosobenzene 
• 62-53-3 aniline 
• 88-67-5 2-Iodobenzoic acid 

Downstream Products

• 494-19-9 9,10-dihydrodibenzazepine 
• 1446358-09-3 N-(2-(chloromethyl)phenyl)benzenamine 
• 1446358-11-7 2-(2-(phenylamino)phenyl)acetonitrile 
• 1194821-23-2 ethyl 2-(2-(phenylamino)phenyl)acetate 
• 1446358-14-0 ethyl 2-(2-(N-phenyl-N-tosylamino)phenyl)acetate 
• 1446358-16-2 1-(2-(N-phenyl-N-tosylamino)phenyl)-2-methylpropan-2-ol 
• 1446358-17-3 3-(2-(N-phenyl-N-tosylamino)benzyl)pentan-3-ol 
• 1446358-18-4 2-(2-(N-phenyl-N-tosylamino)phenyl)-1,1-diphenylethanol 
• 1446358-22-0 2-(2-(N-phenyl-N-tosylamino)phenyl)acetic acid 
• 21737-58-6 10,11-dihydro-5H-dibenzo[b,f]azepin-10-one 
• 1446358-27-5 11,11-diphenyl-10,11-dihydro-5H-dibenzo[b,f]azepine 
• 95888-33-8 2-((N-phenyl)amino)benzaldehyde 
• 13213-90-6 1-phenyl-1H-benzo[d][1,3]oxazin-2(4H)-one 
• 5661-06-3 2,3-dihydro-1H-cyclopenta[b]quinoline 

Relevant articles and documents

Synthesis of Di(hetero)arylamines from Nitrosoarenes and Boronic Acids: A General, Mild, and Transition-Metal-Free Coupling

The synthesis of di(hetero)arylamines by a transition-metal-free cross-coupling between nitrosoarenes and boronic acids is reported. The procedure is experimentally simple, fast, mild, and scalable and has a wide functional group tolerance, including carbonyls, nitro, halogens, free OH and NH groups. It also permits the synthesis of sterically hindered compounds.

PhI(OAc)2-mediated intramolecular oxidative aryl-aldehyde C sp 2-C sp 2 bond formation: Metal-free synthesis of acridone derivatives

A metal-free protocol for direct aryl-aldehyde Csp2-Csp 2 bond formation via a PhI(OAc)2-mediated intramolecular cross-dehydrogenative coupling (CDC) of various 2-(N-arylamino)aldehydes was developed. The novel methodology requires no need of preactivation of the aldehyde group, is applicable to a large variety of functionalized substrates, and most of all provides a convenient approach to the construction of biologically important acridone derivatives.

The chemistry of 2H-3,1-benzoxazine-2,4(1H)-dione (isatoic anhydride). 19. Direct formation of 2-aminobenzyl alcohols from the reduction of N-substituted isatoic anhydrides

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