5341-44-6Relevant articles and documents
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Miller,Ploechl
, p. 2053 Anm. (1892)
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Facile route for green synthesis of N-benzylideneaniline over bimetallic reduced graphene oxide: chemical reactivity of 2,3,4-substituted derivatives of aniline
Aman, Razia,Sadiq, Saima,Ali, Muhammad,Sadiq, Muhammad,Gul, Jehan,Saeed, Khalid,Khan, Adnan Ali,Shah, Sagheer Hussain
, p. 2947 - 2961 (2019/02/28)
Mn–Co-decorated reduced graphene oxide (Mn–Co–rGO) was prepared by modified condensation method and characterized through XRD, SEM, EDX, FTIR and BET surface area analysis. The prepared sample was explored for its activity in the synthesis of N-benzylideneaniline (N-BA) using benzyl alcohol and PhNH2 as precursors. The catalyst has been used efficiently with high activity and selectivity for oxidation of benzyl alcohol to benzaldehyde in the presence of molecular oxygen, which further react with aniline to produced N-BA with sustainable catalytic activity up to five cycles. Furthermore, the effect of the nature and position of the substituent on aniline on the chemical reactivity of the nucleophile was studied theoretically using density functional calculations.
Oxidation of aromatic anils by sodium perborate in aqueous acetic Acid Medium
Venkatesh,Karunakaran
, p. 739 - 744 (2014/06/09)
The kinetics of oxidation of 9 meta- and 15 para- substituted aromatic anils by sodium perborate were investigated in aqueous acetic acid medium. The reaction was second order with respect to aromatic anil and first order with respect to the sodium perborate. The increase of [H+] in this oxidation retards the rate of the reaction. The observed rate constant for the substituents were plotted against the Hammett constant, δ and a non-linear concave downward curve was obtained for the anils with substituents in the aniline moiety. The observed break in the log kobs versus δwas attributed to the transition state whereas the non-linear concave upward curve was observed for the substituents in the benzaldehyde moiety and a non-linear concave upward curve was observed for the substituents in the combination of aniline and benzaldehyde moiety. The electron withdrawing substituents fall on one side of the curve, having a negative ρvalue and the electron releasing substituents fall on the other side, with a positive ρvalue and a suitable mechanism was proposed.