54698-17-8

Basic information

• Product Name: Ethanone, 1-(2,5-dihydroxy-4-methylphenyl)-
• CAS NO: 54698-17-8
• Molecular Formula: C9H10O3
• Molecular Weight: 166.177
• Mol File: 54698-17-8.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: Ethanone, 1-(2,5-dihydroxy-4-methylphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-(2,5-dihydroxy-4-methylphenyl)-(54698-17-8)
• EPA Substance Registry System: Ethanone, 1-(2,5-dihydroxy-4-methylphenyl)-(54698-17-8)

Safety Data

• Hazardous Substances Data: 54698-17-8(Hazardous Substances Data)

Upstream product

• 63076-94-8 2-acetyl-5-methyl-1,4-benzoquinone 
• 107623-90-5 5-Acetyl-2-methyl-hydrochinon-diacetat 
• 7446-70-0 aluminium trichloride 
• 717-27-1 2,5-diacetoxytoluene 
• 109-63-7 boron trifluoride diethyl etherate 
• 14753-08-3 2,5-dimethoxy-p-cymene 
• 95-71-6 2-methylbenzene-1,4-diol 
• 64-19-7 acetic acid 
• 4223-84-1 1-(2-hydroxy-5-methoxy-4-methylphenyl)ethanone 

Downstream Products

• 1369788-12-4 2-O-(α-methyl carboethoxy)-5-methoxy-4-methyl-acetophenone 
• 126570-32-9 5-acetyl-4-hydroxy-2-methylphenyl acetate 
• 1413540-01-8 2-O,5-O-dibenzyl-10,11-epoxy-10,11-dihydrocurcuhydroquinone 
• 1413539-98-6 2-O,5-O-dibenzyl-curcuhydroquinone 
• 1220045-27-1 C₁₁H₁₄O₄ 
• 92157-64-7 2-<2,5-Dimethoxy-4-methyl-phenyl>-milchsaeure-methylester 
• 95295-97-9 Aglykon--methylether; Aglykon-H-leukodimethylether; 2-(4-Methyl-2,5-dimethoxy-phenyl)-propionsaeure 
• 23349-53-3 2-<2,5-Dimethoxy-4-methyl-phenyl>-acrylsaeure 
• 91497-88-0 (2,5-Dimethoxy-4-methyl-phenyl)-glyoxylsaeure-methylester 
• 61042-31-7 (2,5-Dimethoxy-4-methyl-phenyl)-glyoxylsaeure 

Relevant articles and documents

Stereoselective synthesis of Heliannuol G

The first stereoselective synthesis of Heliannuol G has been achieved employing an o-quinone methide intermediate. The present synthesis triumphs over all the drawbacks associated with the reported one and reveals an impressive overall yield of 12.37%.

Erratum: Biomimetic Total Synthesis of Paeoveitol (Org. Lett. (2016) 18: 18 (4578-4581) DOI: 10.1021/acs.orglett.6b02228)

-

Synthesis of heliannane skeletons. Facile preparation of (±)-heliannuol D

Heliannuol D is a natural product with a 7,10-heliannane skeleton, isolated from Helianthus annuus. It has been synthesized in eight steps, in good yield, using a new biomimetic method. Key steps were a Fries rearrangement, a Grignard reaction and, finall